Advances in design of heterogeneous catalysts for pyrolysis of lignocellulosic biomass and bio-oil upgrading

J Grams, A Jankowska, J Goscianska - Microporous and Mesoporous …, 2023 - Elsevier
Lignocellulosic biomass can be converted into more valuable products by high-temperature
treatment causing the formation of bio-oil. However, the complex structure of lignocellulosic …

Recent advances in mass spectrometric studies on the reaction process of biomass pyrolysis

P Liu, H Zhuang, Y Qian, J Yang, Y Pan, Z Zhou… - Fuel Processing …, 2022 - Elsevier
Biomass pyrolysis has arisen great attention for producing clean fuels, valuable chemicals,
and advanced materials. Knowledge on the properties of both final products and …

Tuning the zeolite acidity enables selectivity control by suppressing ketene formation in lignin catalytic pyrolysis

Z Pan, A Puente-Urbina, SR Batool, A Bodi… - Nature …, 2023 - nature.com
Unveiling catalytic mechanisms at a molecular level aids rational catalyst design and
selectivity control for process optimization. In this study, we find that the Brønsted acid site …

In situ mass spectrometric analysis on zeolite-catalyzed pyrolysis of furanic compounds: The role of reactive intermediates

P Liu, W Shao, Z Yang, J Yang, L Jia, Y Pan… - ACS …, 2023 - ACS Publications
Reactive intermediates are essential for determining the reaction mechanism of biomass
pyrolysis. However, these short-life compounds are rarely reported because they are difficult …

Insight into the synergistic reaction mechanism of biomass pseudo components and low-density polyethylene for the production of light aromatics through co-catalytic …

M Huang, L Zhu, W Zhang, L Zhu, Z Ma, D Chen - Fuel, 2022 - Elsevier
Co-feeding of waste plastics during biomass catalytic fast pyrolysis can improve remarkably
the yield of aromatic hydrocarbons. In this work, the simulated biomass by using its model …

Hierarchical beta zeolites assisted aromatics production from lignin via catalytic fast pyrolysis

L Wu, J Liu, L Chen, X Wang, Q Zhou, F Yu… - Chemical Engineering …, 2024 - Elsevier
Converting lignin waste into aromatics is a challenging but crucial aspect of lignin
valorization. Although ZSM-5 zeolite is extensively used in lignin deoxygenation, its 10 …

Investigation on the co-pyrolysis of bamboo sawdust and low-density polyethylene via online photoionization mass spectrometry and machine learning methods

K Yang, K Wu, F Li, L Jia, S Wang, H Zhang - Fuel Processing Technology, 2023 - Elsevier
The high oxygen content of biomass is the limitation for its widespread utilization, and the co-
pyrolysis of biomass feedstock with plastics has gotten much attention by researchers in …

Effect of Cu-modified HZSM-5 zeolites on catalytic pyrolysis of lignin to producing aromatic hydrocarbons

Y Shen, C Liu, C Cui, H Ren, M Gu, H Liu, Z Zhou, F Qi - Fuel, 2024 - Elsevier
Lignin catalytic pyrolysis presents a promising and sustainable approach to producing
aromatic molecules. Herein, we investigated the effect of modified zeolite with copper …

Catalytic pyrolysis mechanism of lignin moieties driven by aldehyde, hydroxyl, methoxy, and allyl functionalization: the role of reactive quinone methide and ketene …

Z Pan, X Wu, A Bodi, JA van Bokhoven… - Green …, 2024 - pubs.rsc.org
The catalytic pyrolysis of guaiacol-based lignin monomers, vanillin, syringol, and eugenol
over commercial HZSM-5 has been investigated using operando Photoelectron Photoion …

Study on the reaction mechanism of nitrogenous compounds in zeolite-catalyzed pyrolysis of blue-green algae

Y Qian, P Liu, H Zhuang, L Chen, L Jia, J Yang… - Fuel Processing …, 2022 - Elsevier
The ex-situ catalytic fast pyrolysis (CFP) of blue-green algae (BGA) and its nitrogenous
model compounds over HZSM-5 was conducted in a microfluidized bed reactor (MFBR) …