1.1. Historic Perspective Silica and doped silica materials obtained via the solution− gelation
(“sol− gel”) inorganic polymerization process are functional materials with an impressive …

A large number of immobilized‐Pd‐catalysts for cross‐coupling reactions have been
introduced in the last decade. Are the observed catalyzed reactions truly heterogeneous or …

One of the most important environmental challenges of modern society is to develop new
catalysts that make possible chemical processes with reduced environmental impact …

Two 3D-hybrid monolithic catalysts containing immobilized copper and palladium species
on a silica support were synthesized by 3D printing and a subsequent surface …

Various requirements for 3D printing raised by actual applications in different fields have
provoked the rapid development of technologies together with various specific materials. A …

In this study, a novel three-dimensional (3D)-OMm-Co3O4/SiO2-0.5 AP (OMm= ordered
macro–meso porous, AP= aluminum phosphate) monolithic catalyst was for the first time …

A tricatalytic compartmentalized system that immobilizes metallic species to perform one-pot
sequential functionalization is described: a three-dimensional (3D)-printed palladium …

The derivatization of functional organic fragments with triethoxysilyl groups to afford
hydrolyzable organosilanes with targeted properties using the copper-catalyzed alkyne …

For this work, an integrated system composed of a polypropylene reactor and a palladium
on silica monolithic catalyst was designed and manufactured by 3D‐printing. These devices …

The copper-catalyzed 'click silylation'has been exploited for the chemical modification of γ-
azidopropyltriethoxysilane (AzPTES) with a wide range of terminal alkynes (1a–1v) in a one …