The direct functionalization of C (sp3)–H bonds represents one of the most investigated
approaches to develop new synthetic methodology. Among the available strategies for …

Organosulfur functionalities are ubiquitous in nature, pharmaceuticals, agrochemicals,
materials and flavourants. Historically, these moieties were introduced almost exclusively …

Sulfinates are important lynchpin intermediates in pharmaceutical production; however, their
synthesis via photoredox catalysis is challenging because of their facile oxidation. We …

The coupling of carboxylic acids and amines to form amide linkages is the most commonly
performed reaction in the pharmaceutical industry. Herein, we report a new strategy that …

Recently, radical fluorosulfonylation is emerging as an appealing approach for the synthesis
of sulfonyl fluorides, which are highly in demand in various disciplines, particularly in …

The reactivity of the sulfonyl group varies dramatically from nucleophilic sulfinates through
chemically robust sulfones to electrophilic sulfonyl halides—a feature that has been used …

Although the transition metal-catalyzed radical fluorine atom transfer (FAT) strategy has
emerged as a powerful tool for the construction of C–F bonds, to our knowledge, this …

The intermediate oxidation state of sulfoxides is central to the plethora of their applications in
chemistry and medicine, yet it presents challenges for an efficient synthetic access, limiting …

Dual catalytic systems involving photocatalytic activation and transition metal-catalyzed
steps have enabled innovative approaches to the construction of carbon–carbon and carbon …

C− H thioarylation of hydrocarbon building blocks is a highly desirable synthetic
transformation because of its prevalence in various pharmaceuticals and organic functional …