Octacyanidometallates have been successfully employed in the design of heterometallic
coordination systems offering a spectacular range of desired physical properties with great …

Complete overview of octacyanidometallate polymetallic assemblies is presented from a
novel viewpoint of the importance of incorporated ligands. The ligands are classified …

Photomagnetism in molecular systems is a new development in molecular magnetism. It
traces back to 1982 and 1984 when a transient effect and then the light-induced excited-spin …

A huge increase in the magnetization of two coordination chains based on tetravalent
octacyanidometalates (WIV and MoIV) is observed on irradiation with 436 nm light, while no …

Three members of the family of trigonal bipyramidal (TBP) complexes of general formula [M
(tmphen) 2] 3 [M′(CN) 6] 2 (tmphen= 3, 4, 7, 8-tetramethyl-1, 10-phenanthroline) or [M3M …

The aim and the scope of this review is to show the results of ten years of research following
the first reports on magnetic and photomagnetic assemblies constructed from [M (CN) 8] n …

We elaborate here why the antiferromagnetically ordered GdCrO 3 responds in a
diamagnetic way under certain conditions by monitoring the evolution of the microscopic …

Ab initio calculations show that a possible mechanism for the photomagnetism in copper
octacyanomolybdate compounds consists of the initial excitation of the diamagnetic CuII …

High level ab initio calculations on the photoinduced high-spin molecule [Mo (CN) 2 (CN–
Cu (tris (2-aminoethyl) amine) 6] 8+ are reported. The calculations indicate that the …

Octacyanidometallates have been proven to be very useful molecular building blocks for the
construction of various molecular materials with a strong emphasis on magnetic properties …