Keep it tight: a crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes

AV Paderina, IO Koshevoy, EV Grachova - Dalton Transactions, 2021 - pubs.rsc.org
Copper subgroup metal ions in the+ 1 oxidation state are classical candidates for
aggregation via non-covalent metal–metal interactions, which are supported by a number of …

A N-Heterocyclic Carbene-Stabilized Coinage Metal-Chalcogenide Framework with Tunable Optical Properties

AM Polgar, F Weigend, A Zhang… - Journal of the …, 2017 - ACS Publications
A new class of coinage-metal chalcogenide compounds [Au4M4 (μ3-E) 4 (IPr) 4](M= Ag, Au;
E= S, Se, Te) has been synthesized from the combination of N-heterocyclic carbene-ligated …

White‐Light Generation Upon In‐Situ Amorphization of Single Crystals of [{(Me3P)3AuSn}(PhSn)3S6] and [{(Et3P)3AgSn}(PhSn)3S6]

E Dornsiepen, F Dobener, N Mengel… - Advanced Optical …, 2019 - Wiley Online Library
In order to gain more information on the white‐light generation by amorphous molecular
materials, the influence of metal complex substituents on the photophysical properties of …

Tuning the Metal/Chalcogen Composition in Copper (I)–Chalcogenide Clusters with Cyclic (Alkyl)(amino) carbene Ligands

AM Polgar, A Zhang, F Mack, F Weigend… - Inorganic …, 2019 - ACS Publications
A series of phosphorescent homo-and heterometallic copper (I)–chalcogenide clusters
stabilized by cyclic (alkyl)(amino) carbene ligands [Cu4M4 (μ3-E) 4 (CAACCy) 4](M= Cu, Ag …

Homoleptic Group 13 Trimethylsilylchalcogenolato Metalates [M(ESiMe3)4] (M = Ga, In; E = S, Se): Metastable Precursors for Low-Temperature Syntheses of …

J Guschlbauer, T Vollgraff, J Sundermeyer - Inorganic Chemistry, 2019 - ACS Publications
We communicate the synthesis and full characterization of so far unknown tetrakis
(trimethylsilylsulfido) and-(trimethylsilylselenido) gallates and indates in form of their organic …

Synthesis and characterization of ITr-protected group 11 metal trimethylsilylchalcogenolates

DR Nahhas, JF Corrigan - Canadian Journal of Chemistry, 2021 - cdnsciencepub.com
This work describes the synthesis of group 11 metal trimethylsilylchalcogenolate complexes
[(ITr) M-ESiMe3] stabilized by the large NHC ligand bis-1, 3-tritylimidazole-2-ylidene (ITr) …

N-Heterocyclic Carbene Ligated Group 11 Trimethylsilylchalcogenolates: Building Blocks for Heterometallic Chalcogenide Molecules

DR Nahhas - 2020 - search.proquest.com
The synthesis of heterometallic chalcogenide molecules requires the continued
investigation into the appropriate reagents necessary to introduce metal–chalcogen bonds …