Benziporphyrins were first discovered over 20 years ago. Although initially they were considered to be a chemical curiosity, a wide range of benzene-containing porphyrinoid …
The unique environment within the core of carbaporphyrinoid systems provides a platform to explore unusual organometallic chemistry. The ability of these structures to form stable …
The scientific interest in porphyrinoid based materials is steady growing, since porphyrinoids are not only of biological relevance, but they also show interesting spectroscopic properties …
meso-Tetraphenyl meta-benziporphyrins are nonaromatic macrocycles which can be changed to antiaromatic by fusing the core benzene ring with one of the adjacent meso …
K Hurej, M Pawlicki, L Szterenberg… - Angewandte Chemie …, 2016 - Wiley Online Library
The contraction of benzene is one of an exclusive group of reactions where the cleavage of aromatic structure is of fundamental importance. Rhodium (III) m‐benziporphyrin undergoes …
Magnetically induced current densities have been calculated and analyzed for a number of synthesized carbachlorins and carbaporphyrins using density functional theory and the …
Fluorene‐based tripyrrane has been used as a fused precursor to synthesize three novel examples of nonaromatic meso‐fused thia and selenabenzihomoporphyrin (2.1. 1.1) s by …
SC Fosu, GM Ferrence, TD Lash - The Journal of Organic …, 2014 - ACS Publications
Dimethoxybenzitripyrranes were prepared in excellent yields by reacting benzene dicarbinols with BF3· Et2O and excess pyrrole in refluxing 1, 2-dichloroethane. Reaction …
TD Lash - Advances in Heterocyclic Chemistry, 2022 - Elsevier
Core-modified porphyrins have been widely investigated and exhibit diverse characteristics. Heteroporphyrins of this type retain the framework found in true porphyrins but have O, S …