An important goal of modern synthetic chemistry is the development of highly efficient and
selective processes that minimize the formation of waste, which are desirable for economy …

A polystyrene-supported 1, 5, 7-triazabicyclodec-5-ene (TBD) was used as a highly
recyclable and stable catalyst for the conversion of epoxy amines into various 2-oxazolidone …

The study of a Mitsunobu reaction is an important topic. Denton and co-workers first reported
a novel (2-hydroxybenzyl) diphenylphosphine oxide for realizing the catalytic Mitsunobu …

Due to their inert nature and low reactivities, the dehydrative version of the MA reaction has
not been achieved under metal-free conditions. Here, we develop a direct and efficient metal …

A family of polystyrene-supported (phosphoramidite, olefin) ligands L1–L4, based on the
original design by Defieber and Carreira, has been developed and applied in iridium …

A set of structurally analogous, albeit electronically distinct, phosphamides (1aa-10aa) is
prepared, and the effect of the electronic amendment due to p-substitution has been tested …

Herein we demonstrate the application of continuous flow technology to the synthesis of
hydrazine derivatives by deoxygenation of free alcohols with di-tert-butylazodicarboxylate …

Thiamine (VB1) has been proved to be a powerful biocatalyst for various organic
transformations. VB1 offers several unique advantages, such as economical, non‐toxic …

Solid polymer brush-supported molecular catalysts generally exhibit activity comparable to
molecular catalysts, but they suffer the problems of decreased activity with increasing …

Chiral phosphoric acids (CPAs) and their salts are the privileged catalysts in a plethora of
asymmetric transformations. All of the scaffolds of efficient CPAs rely on C2‐symmetry and …