Strong metal–support interaction in heterogeneous catalysts

Z Luo, G Zhao, H Pan, W Sun - Advanced Energy Materials, 2022 - Wiley Online Library
Strong metal–support interaction (SMSI) in supported metal catalysts, typically accompanied
by the formation of encapsulation layers over metal nanoparticles, has drawn intense …

Single-atom catalysts based on the metal–oxide interaction

R Lang, X Du, Y Huang, X Jiang, Q Zhang… - Chemical …, 2020 - ACS Publications
Metal atoms dispersed on the oxide supports constitute a large category of single-atom
catalysts. In this review, oxide supported single-atom catalysts are discussed about their …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Electronic metal–support interaction modulates single-atom platinum catalysis for hydrogen evolution reaction

Y Shi, ZR Ma, YY Xiao, YC Yin, WM Huang… - Nature …, 2021 - nature.com
Tuning metal–support interaction has been considered as an effective approach to modulate
the electronic structure and catalytic activity of supported metal catalysts. At the atomic level …

Pt Single Atoms Supported on N‐Doped Mesoporous Hollow Carbon Spheres with Enhanced Electrocatalytic H2‐Evolution Activity

P Kuang, Y Wang, B Zhu, F Xia, CW Tung… - Advanced …, 2021 - Wiley Online Library
The electronic metal–support interaction (EMSI) plays a crucial role in catalysis as it can
induce electron transfer between metal and support, modulate the electronic state of the …

An electron-hole rich dual-site nickel catalyst for efficient photocatalytic overall water splitting

X Yan, M Xia, H Liu, B Zhang, C Chang, L Wang… - Nature …, 2023 - nature.com
Photocatalysis offers an attractive strategy to upgrade H2O to renewable fuel H2. However,
current photocatalytic hydrogen production technology often relies on additional sacrificial …

High-entropy alloys as a platform for catalysis: progress, challenges, and opportunities

Y Xin, S Li, Y Qian, W Zhu, H Yuan, P Jiang, R Guo… - Acs …, 2020 - ACS Publications
High-entropy alloys (HEAs), which are defined as near-equimolar alloys of five or more
elements, are attracting ever increasing attention because of the unique properties in a …

Self‐accommodation induced electronic metal–support interaction on ruthenium site for alkaline hydrogen evolution reaction

C Li, SH Kim, HY Lim, Q Sun, Y Jiang… - Advanced …, 2023 - Wiley Online Library
Tuning the metal‐support interaction of supported metal catalysts has been found to be the
most effective approach to modulating electronic structure and improving catalytic …

Well-defined materials for heterogeneous catalysis: from nanoparticles to isolated single-atom sites

Z Li, S Ji, Y Liu, X Cao, S Tian, Y Chen, Z Niu… - Chemical …, 2019 - ACS Publications
The use of well-defined materials in heterogeneous catalysis will open up numerous new
opportunities for the development of advanced catalysts to address the global challenges in …

Supported metal clusters: fabrication and application in heterogeneous catalysis

C Dong, Y Li, D Cheng, M Zhang, J Liu, YG Wang… - ACS …, 2020 - ACS Publications
Different from isolated metal atoms and large metal nanoparticles (NPs), supported metal
clusters (SMCs) possess distinct geometric and electronic structures and thus exhibit …