Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering

YN Zhou, JJ Li, TT Wang, YY Wu, ZH Luo - Progress in Polymer Science, 2022 - Elsevier
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …

Radical polymerization of acrylic monomers: An overview

N Ballard, JM Asua - Progress in Polymer Science, 2018 - Elsevier
Since their discovery and development in the 20th century, acrylic polymers have become
an integral part of numerous industries and are used in a myriad of applications. As is true …

Radical polymerization of acrylates, methacrylates, and styrene: Biobased approaches, mechanism, kinetics, secondary reactions, and modeling

T Pirman, M Ocepek, B Likozar - Industrial & Engineering …, 2021 - ACS Publications
Biobased polymer molecules are a goal for the future. Here, the different intermediate
pathways toward renewable structural constituents, which can substitute petrochemically …

Biobased acrylic pressure-sensitive adhesives

MA Droesbeke, R Aksakal, A Simula, JM Asua… - Progress in Polymer …, 2021 - Elsevier
The ever-increasing regulations within the adhesives industry and the continuous demand
for more sustainability, have led to the development of environmentally more suitable …

Mechanics of elastomeric molecular composites

P Millereau, E Ducrot, JM Clough… - Proceedings of the …, 2018 - National Acad Sciences
A classic paradigm of soft and extensible polymer materials is the difficulty of combining
reversible elasticity with high fracture toughness, in particular for moduli above 1 MPa. Our …

Playing with process conditions to increase the industrial sustainability of poly (lactic acid)-based materials

K De Smit, YW Marien, PHM Van Steenberge… - Reaction Chemistry & …, 2023 - pubs.rsc.org
Polylactic acid (PLA) is an important polymer for the replacement of oil-based polymers in
the biomedical field as well as for degradable single use polymeric materials. To fully exploit …

Impact of side reactions on molar mass distribution, unsaturation level and branching density in solution free radical polymerization of n-butyl acrylate under well …

M Edeleva, YW Marien, PHM Van Steenberge… - Polymer …, 2021 - pubs.rsc.org
The radical chemistry of polyacrylate synthesis is non-trivial, due to a significant amount of
side reactions. Backbiting transforms conventional secondary end-chain radicals (ECRs) in …

How phase transfer increases the number of kinetic regimes from three to seven in nitroxide mediated polymerization of n-butyl acrylate in aqueous miniemulsion

E Zeinali, YW Marien, SR George… - Chemical Engineering …, 2023 - Elsevier
One of the challenges in reversible deactivation radical polymerization (RDRP) in
miniemulsion is identifying the optimal average particle size (dp), offering both high reaction …

Designing acrylic latexes for pressure‐sensitive adhesives: a review

N Ballard - Polymer International, 2024 - Wiley Online Library
Pressure‐sensitive adhesives (PSAs) are essential components of a large number of
commercial products. The immense range of substrates that are required to be bonded …

Preparation of environmentally friendly acrylic pressure-sensitive adhesives by bulk photopolymerization and their performance

M Zhu, Z Cao, H Zhou, Y Xie, G Li, N Wang, Y Liu… - RSC …, 2020 - pubs.rsc.org
Polyacrylic pressure-sensitive adhesives (PSAs) based on butyl acrylate (BA), 2-
hydroxyethyl acrylate (HEA), and acrylic acid (AA) were prepared by a bulk polymerization …