Corroles at work: A small macrocycle for great applications
C Di Natale, CP Gros, R Paolesse - Chemical Society Reviews, 2022 - pubs.rsc.org
Corrole chemistry has witnessed an impressive boost in studies in the last 20 years, thanks
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …
The story of 5d metallocorroles: from metal–ligand misfits to new building blocks for cancer phototherapeutics
Conspectus Porphyrin chemistry is Shakespearean: over a century of study has not withered
the field's apparently infinite variety. Heme proteins continually astonish us with novel …
the field's apparently infinite variety. Heme proteins continually astonish us with novel …
2D Copper Tetrahydroxyquinone Conductive Metal–Organic Framework for Selective CO2 Electrocatalysis at Low Overpotentials
Metal–organic frameworks (MOFs) are promising materials for electrocatalysis; however,
lack of electrical conductivity in the majority of existing MOFs limits their effective utilization in …
lack of electrical conductivity in the majority of existing MOFs limits their effective utilization in …
The Myth of d8 Copper(III)
IM DiMucci, JT Lukens, S Chatterjee… - Journal of the …, 2019 - ACS Publications
Seventeen Cu complexes with formal oxidation states ranging from CuI to CuIII are
investigated through the use of multiedge X-ray absorption spectroscopy (XAS) and density …
investigated through the use of multiedge X-ray absorption spectroscopy (XAS) and density …
Interfacial oxygen vacancy modulated ZIF-8-derived ZnO/CuS for the photocatalytic degradation of antibiotic and organic pollutants: DFT calculation and degradation …
Fabricating oxygen vacancies (Vo) is an effective approach to enhance photocatalytic
performance, but its effect on the interfacial charge transfer pathway remains unelucidated to …
performance, but its effect on the interfacial charge transfer pathway remains unelucidated to …
Formation of a Copper(II)–Tyrosyl Complex at the Active Site of Lytic Polysaccharide Monooxygenases Following Oxidation by H2O2
A Paradisi, EM Johnston, M Tovborg… - Journal of the …, 2019 - ACS Publications
Hydrogen peroxide is a cosubstrate for the oxidative cleavage of saccharidic substrates by
copper-containing lytic polysaccharide monooxygenases (LPMOs). The rate of reaction of …
copper-containing lytic polysaccharide monooxygenases (LPMOs). The rate of reaction of …
Seven clues to ligand noninnocence: the metallocorrole paradigm
Conspectus Noninnocent ligands do not allow an unambiguous definition of the oxidation
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …
Generation and Aerobic Oxidative Catalysis of a Cu (II) Superoxo Complex Supported by a Redox-Active Ligand
Cu systems feature prominently in aerobic oxidative catalysis in both biology and synthetic
chemistry. Metal ligand cooperativity is a common theme in both areas as exemplified by …
chemistry. Metal ligand cooperativity is a common theme in both areas as exemplified by …
Ultrafast dynamics and strong two-photon absorption properties of nonplanar β-functionalized “push–pull” copper corroles with a mixed substituent pattern
A new series of nonplanar and unsymmetrically β-functionalized “push–pull” copper
corroles, CuTPC (CHO) R7 [R= H, Br, Ph, Me, or 2-thienyl (Th)], were synthesized and …
corroles, CuTPC (CHO) R7 [R= H, Br, Ph, Me, or 2-thienyl (Th)], were synthesized and …
Cation Incorporation into Copper Oxide Lattice at Highly Oxidizing Potentials
Electrolyte cations can have significant effects on the kinetics and selectivity of
electrocatalytic reactions. We show an atypical mechanism through which electrolyte cations …
electrocatalytic reactions. We show an atypical mechanism through which electrolyte cations …