Atomic-layer Fe2O3-modified 2D porphyrinic metal-organic framework for enhanced photocatalytic disinfection through electron-withdrawing effect

J Li, Z Cui, Y Zheng, X Liu, Z Li, H Jiang, S Zhu… - Applied Catalysis B …, 2022 - Elsevier
In this work, an atomic-layer Fe 2 O 3-modified two-dimensional (2D) porphyrinic metal-
organic framework (MOF) was prepared (2D MOF-Fe 2 O 3), which exhibits unique …

Understanding the prototype catalyst TiO2 surface with the help of density functional theory calculation

R Wang, B Wang, AS Abdullahi… - Wiley Interdisciplinary …, 2024 - Wiley Online Library
Titanium dioxide (TiO2) is one of the most technologically promising oxides with a broad
range of catalytic and photocatalytic activities. Theoretical modeling, especially density …

Resolving the heat of trimethylaluminum and water atomic layer deposition half-reactions

AR Bielinski, EP Kamphaus, L Cheng… - Journal of the …, 2022 - ACS Publications
Atomic layer deposition (ALD) is a surface synthesis technique that is characterized by self-
limiting reactions between gas-phase precursors and a solid substrate. Although ALD …

Nucleation dependence of atomic layer deposition on diamond surface termination

JC Jones, N Delegan, FJ Heremans, ABF Martinson - Carbon, 2023 - Elsevier
Surface termination and interfacial interactions are critical for advanced solid-state quantum
applications. In this paper, we demonstrate that atomic layer deposition (ALD) can both …

Site-Selective Atomic Layer Deposition at Thermally Generated Surface Oxygen Vacancies on Rutile TiO2

JC Jones, EP Kamphaus, JR Guest… - Chemistry of …, 2023 - ACS Publications
Unique atomic arrangements (ie, defects) on material surfaces may exhibit distinctive
reactivity that affords opportunities for selective surface chemistry exclusively at those sites …

Anatase TiO2 Surface Hydration: Infrared Vibrational Assignment and Facet-Specific Stability

C Luo, ZD Hood, ABF Martinson… - The Journal of Physical …, 2024 - ACS Publications
Anatase TiO2 nanoparticles support a subtle diversity of surface aqua and hydroxy
coordination environments that are characteristic of distinct facets and defect sites. The …

Site-Selective Atomic Layer Deposition on Rutile TiO2: Selective Hydration as a Route to Target Point Defects

EP Kamphaus, JC Jones, N Shan… - The Journal of …, 2023 - ACS Publications
Routes to area-and especially site-selective atomic layer deposition (ALD) remain an
enticing challenge in precision surface science, despite the potentially game-changing …

Fluorination of TiN, TiO2, and SiO2 Surfaces by HF toward Selective Atomic Layer Etching (ALE)

JH Jung, H Oh, B Shong - Coatings, 2023 - mdpi.com
As semiconductor devices become miniaturized, the importance of the molecular-level
understanding of the fabrication processes is growing. Titanium nitride (TiN) is an important …

Resolving the Heat Generated from ZrO2 Atomic Layer Deposition Surface Reactions

AR Bielinski, EP Kamphaus, L Cheng… - Angewandte Chemie …, 2023 - Wiley Online Library
In situ pyroelectric calorimetry and spectroscopic ellipsometry were used to investigate
surface reactions in atomic layer deposition (ALD) of zirconium oxide (ZrO2). Calibrated and …

Mechanistically Informed Strategies for Site-Selective Atomic Layer Deposition

JC Jones, EP Kamphaus, L Cheng, C Liu… - Chemistry of …, 2024 - ACS Publications
While atomic layer deposition (ALD) processes from across the periodic table have been
designed to deposit conformal thin films, an atomistic view of disparate substrate sites …