ICTAC Kinetics Committee recommendations for analysis of thermal polymerization kinetics

S Vyazovkin, D Achilias, X Fernandez-Francos… - Thermochimica acta, 2022 - Elsevier
The present recommendations have been developed by the Kinetics Committee of the
International Confederation for Thermal Analysis and Calorimetry (ICTAC). The …

Controversies on the mechanism and kinetics of emulsion polymerization: An updated critical review

J Herrera-Ordonez - Advances in Colloid and Interface Science, 2023 - Elsevier
Conventional emulsion polymerization (EP) is a process via free radicals whose driving
force for its development has been its versatility to generate polymer colloids with ad hoc …

How chain length dependencies interfere with the bulk RAFT polymerization rate and microstructural control

N De Rybel, PHM Van Steenberge, MF Reyniers… - Chemical Engineering …, 2018 - Elsevier
A pseudo-steady state based (PSSA) deterministic solution strategy is presented to calculate
the concentrations of single and multi-arm macrospecies types in reversible addition …

Scale-up of Emulsion Polymerisation up to 100 L and with a Polymer Content of up to 67 wt%, Monitored by Photon Density Wave Spectroscopy

LI Jacob, W Pauer - Polymers, 2022 - mdpi.com
The scale-up process of the high solid content (up to 67 wt%) emulsion polymerisation of
vinyl acetate and Versa® 10 from 1 L over 10 L to 100 L was investigated. An emulsion …

Interplay of head, tail, and mid-chain radicals in bulk free-radical and reversible degenerative addition fragmentation chain-transfer polymerizations of vinyl acetate

N De Rybel, PHM Van Steenberge, MF Reyniers… - …, 2019 - ACS Publications
A detailed kinetic model for isothermal bulk free-radical and degenerative reversible
addition–fragmentation chain-transfer (RAFT) polymerizations of vinyl acetate is presented …

An experimental and theoretical study of butyl methacrylate in situ radical polymerization kinetics in the presence of graphene oxide nanoadditive

M Michailidis, GD Verros, EA Deliyanni… - Journal of Polymer …, 2017 - Wiley Online Library
The butyl methacrylate radical polymerization kinetics in the presence of graphene oxide
nanoadditive is studied both experimentally and theoretically. The experimental study …

Influence of redox initiator component ratios on the emulsion copolymerisation of vinyl acetate and neodecanoic acid vinyl ester

LI Jacob, W Pauer, B Schroeter - RSC advances, 2022 - pubs.rsc.org
Redox initiated emulsion polymerisation of vinyl acetate and neodecanoic acid vinyl ester
was investigated at temperatures ranging from− 1° C to 87° C (initiation temperature …

Effect of the side ethylene glycol and hydroxyl groups on the polymerization kinetics of oligo (ethylene glycol methacrylates). An experimental and modeling …

MN Siddiqui, DS Achilias, HH Redhwi - Polymer Chemistry, 2020 - pubs.rsc.org
Polymers based on methacrylates bearing short oligo (ethylene glycol) side parts constitute
a modern class of stimuli-responsive, biocompatible materials exhibiting several important …

Unexpected secondary nucleation in poly (vinyl acetate) nanoparticle synthesis by ab initio batch emulsion polymerization using poly (vinyl alcohol) as surfactant

G Rocha‐Botello, R Olvera‐Guillen… - Macromolecular …, 2019 - Wiley Online Library
Kinetic aspects of the vinyl acetate ab initio batch emulsion polymerization using poly (vinyl
alcohol) to produce polymer nanoparticles are studied. The initial nucleation step is followed …

In-line monitoring of latex-particle size during emulsion polymerizations with a high polymer content of more than 60%

LI Jacob, W Pauer - RSC advances, 2020 - pubs.rsc.org
The photon density wave (PDW) spectroscopy is established in the fields of biochemistry
and food chemistry as an online analytical method for the determination of mean particle …