Organic peroxy radicals (often abbreviated RO2) play a central role in the chemistry of the
Earth's lower atmosphere. Formed in the atmospheric oxidation of essentially every organic …

The importance of hydrocarbons in the Earth's troposphere has been recognized since the
1950s, when their contribution (along with that of NOx, ie, NO and NO2) to urban (Los …

Chlorine atoms (Cl) are highly reactive toward hydrocarbons in the Earth's troposphere,
including the greenhouse gas methane (CH4). However, the regional and global CH4 sink …

Very short‐lived substances (VSLS), including dichloromethane (CH2Cl2), chloroform
(CHCl3), perchloroethylene (C2Cl4), and 1, 2‐dichloroethane (C2H4Cl2), are a …

The reactions of Cl atoms with methane and three chlorinated methanes (CH3Cl, CH2Cl2,
and CHCl3) have been studied experimentally using the discharge flow/resonance …

The gas-phase photooxidations of CCl4, CHCl3, CH2Cl2 and their binary mixtures in an O2
stream were studied in a flow reactor under various experimental conditions using a low …

Product yield studies indicate that the reaction of organic peroxy radicals (RO2) with
hydroperoxy radicals (HO2) may proceed via four reaction channels: While is the dominant …

A kinetic reactor system is described which couples pulsed laser photolytic production of
radicals with continuous laser excitation cavity ring-down spectroscopic detection in the near …

The gas-phase reaction of Cl atoms with benzene has been studied using both experimental
and computational methods. The bulk of the kinetic data were obtained using steady-state …

In an attempt to understand the mechanism of the reaction of alkylperoxy radicals with
hydroperoxy radical, a key reaction in both atmospheric and combustion chemistry, the …