Soft elasticity in main chain liquid crystal elastomers

S Dey, DM Agra-Kooijman, W Ren, PJ McMullan… - Crystals, 2013 - mdpi.com
Main chain liquid crystal elastomers exhibit several interesting phenomena, such as three
different regimes of elastic response, unconventional stress-strain relationship in one of …

Strong, resilient, and sustainable aliphatic polyester thermoplastic elastomers

A Watts, N Kurokawa, MA Hillmyer - Biomacromolecules, 2017 - ACS Publications
Thermoplastic elastomers (TPEs) composed of ABA block polymers exhibit a wide variety of
properties and are easily processable as they contain physical, rather than chemical, cross …

Stress relaxation, dynamics, and plasticity of transient polymer networks

F Meng, RH Pritchard, EM Terentjev - Macromolecules, 2016 - ACS Publications
We propose a theoretical framework for dealing with a transient polymer network
undergoing small deformations, based on the rate of breaking and reforming of network …

Multiscale modeling of polymer materials using field-theoretic methodologies: a survey about recent developments

SA Baeurle - Journal of Mathematical Chemistry, 2009 - Springer
Understanding the chemistry and physics of polymer systems challenges scientists from a
wide spectrum of research areas, ranging from polymer science to molecular electronic …

Enhanced mechanical properties of aliphatic polyester thermoplastic elastomers through star block architectures

S Liffland, MA Hillmyer - Macromolecules, 2021 - ACS Publications
A series of sustainable aliphatic polyester thermoplastic elastomers (APTPEs) consisting of
multi-arm star polymers with arms of poly (l-lactide)-b-poly (γ-methyl-ε-caprolactone) were …

High Performance Star Block Aliphatic Polyester Thermoplastic Elastomers Using PDLA-b-PLLA Stereoblock Hard Domains

S Liffland, M Kumler, MA Hillmyer - ACS Macro Letters, 2023 - ACS Publications
Star block (ABC) 4 terpolymers consisting of a rubbery poly (γ-methyl-ε-
caprolactone)(PγMCL)(C) core and hard poly (l-lactide)(PLLA)(B) and poly (d …

Novel covalent adaptable networks (CANs) of ethylene/1-octene copolymers (EOCs) made by free-radical processing: comparison of structure–property relationships …

B Chen, LM Fenimore, Y Chen, SM Barbon… - Polymer …, 2023 - pubs.rsc.org
Ethylene-based copolymers such as ethylene/1-octene copolymers (EOCs) are commonly
used in blends for thermoplastic elastomers, foams, and consumer articles. These blends …

Polyethylene vitrimers via silyl ether exchange reaction

A Zych, R Pinalli, M Soliman, J Vachon, E Dalcanale - Polymer, 2020 - Elsevier
Functional polyethylene (PE) bearing pendant hydroxyl groups was dynamically crosslinked
via reactive extrusion using commercially available N, N′-Bis [3-(trimethoxysilyl) propyl] …

Elasticity and relaxation in full and partial vitrimer networks

F Meng, MO Saed, EM Terentjev - Macromolecules, 2019 - ACS Publications
We develop a continuum model of the dynamic-mechanical response of vitrimers, where the
elastic energy of the material accounts for the conserved number of the crosslinks in the …

Thermoreversible ion gels with tunable melting temperatures from triblock and pentablock copolymers

Y He, TP Lodge - Macromolecules, 2008 - ACS Publications
We demonstrate a way to tune the critical gelation temperature (T gel) for thermoreversible
ion gels. Thermoreversible ion gels were prepared previously through the self-assembly of …