Recent advances in thermoplastic elastomers from living polymerizations: Macromolecular architectures and supramolecular chemistry

W Wang, W Lu, A Goodwin, H Wang, P Yin… - Progress in polymer …, 2019 - Elsevier
Thermoplastic elastomers (TPEs) have found use in a wide range of applications, such as
adhesives, elastomers, coatings, fibers, and in additive manufacturing techniques such as …

Synthesis of well-defined multigraft copolymers

D Uhrig, J Mays - Polymer Chemistry, 2011 - pubs.rsc.org
This short review article focuses on significant developments made in the pursuit of well-
defined graft copolymers over the past decade or so. The state-of-the-art for synthesis of the …

Tough and sustainable graft block copolymer thermoplastics

J Zhang, T Li, AM Mannion, DK Schneiderman… - ACS Macro …, 2016 - ACS Publications
Fully sustainable poly [HPMC-g-(PMVL-b-PLLA)] graft block copolymer thermoplastics were
prepared from hydroxypropyl methylcellulose (HPMC), β-methyl-δ-valerolactone (MVL), and …

A novel architecture toward third-generation thermoplastic elastomers by a grafting strategy

F Jiang, Z Wang, Y Qiao, Z Wang, C Tang - Macromolecules, 2013 - ACS Publications
Thermoplastic elastomers (TPEs) are ever sought using a simple robust synthetic approach.
Widely successful first-generation TPEs rely on microphase-separated ABA triblock …

Toward sustainable elastomers from the grafting-through polymerization of lactone-containing polyester macromonomers

L Fournier, DM Rivera Mirabal, MA Hillmyer - Macromolecules, 2022 - ACS Publications
As the need for renewable and degradable alternative plastics grows, efforts have been
made to develop biobased polymer architectures with tunable properties. We developed the …

Sustainable thermoplastic elastomers derived from renewable cellulose, rosin and fatty acids

Y Liu, K Yao, X Chen, J Wang, Z Wang, HJ Ploehn… - Polymer …, 2014 - pubs.rsc.org
Two series of graft copolymers, cellulose-g-poly (n-butyl acrylate-co-dehydroabietic ethyl
methacrylate)(Cell-gP (BA-co-DAEMA)) and cellulose-g-poly (lauryl methacrylate-co …

Fabrication of UV-absorbent cellulose-rosin based thermoplastic elastomer via “graft from” ATRP

C Lu, J Yu, C Wang, J Wang, F Chu - Carbohydrate polymers, 2018 - Elsevier
Cellulose-rosin based thermoplastic elastomers with UV absorption properties were
fabricated by a combination of rosin, poly (butyl acrylate)(PBA) and ethyl cellulose (EC) via …

Comb Polyurethanes Consisting of Hard Segment Backbones and Dangling Soft Segments for Tailoring Mechanical Properties of Thermoplastics

D Aoki, H Yoshida, H Ajiro - Macromolecules, 2024 - ACS Publications
Graft polymers, including comb and bottlebrush polymers, have emerged as a topological
molecular design for tailoring elastic material properties, relying on structural parameters …

Synthesis and rheology of branched multiblock polymers based on polylactide

AM Mannion, FS Bates, CW Macosko - Macromolecules, 2016 - ACS Publications
To improve the toughness and processability of poly (lactic acid)(PLA), a branched
multiblock polymer was prepared from d, l-lactide and ε-decalactone. A hydroxy telechelic …

Sustainable thermoplastic elastomers derived from cellulose, fatty acid and furfural via ATRP and click chemistry

J Yu, C Lu, C Wang, J Wang, Y Fan, F Chu - Carbohydrate polymers, 2017 - Elsevier
Cellulose-based thermoplastic elastomers (TPEs) have attracted considerable attention
because of their rigid backbone, good mechanical properties, renewable nature and …