This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …

Since the first heavy alkene analogues of germanium and tin were isolated in 1976, followed
by West's disilene in 1981, the chemistry of stable group 14 dimetallenes and dimetallynes …

Since the latter quarter of the twentieth century, main group chemistry has undergone
significant advances. Power's timely review in 2010 highlighted the inherent differences …

The creative design and exploration of new bonding motifs and molecular architectures in
main group chemistry have pushed the boundaries of reactivity in this field of research. In …

Since the discovery that the so‐called “double‐bond” rule could be broken, the field of
molecular main group multiple bonds has expanded rapidly. With the majority of …

Fundamental research on germanium as the central element in compounds for bond
activation chemistry and catalysis has achieved significant feats over the last two decades …

The uptake and release of small molecules continue to be challenging tasks of utmost
importance in synthetic chemistry. The combination of such small molecule activation with …

The large steric profile of the N-heterocyclic boryloxy ligand,–OB (NDippCH) 2, and its ability
to stabilize the metal-centered HOMO, are exploited in the synthesis of the first example of a …

Major advances in the chemistry of 5th and 6th row heavy p-block element compounds have
recently uncovered intriguing reactivity patterns towards small molecules such as H2, CO2 …

Abstract Tetrylidynes [(Me3P) 2 (Ph3P) Rh≡ SnAr*](10) and [(Me3P) 2 (Ph3P) Rh≡
PbAr*](11) are accessed for the first time via dehydrogenation of dihydrides [(Ph3P) …