Synthesis of monofluoroalkenes: a leap forward

M Drouin, JD Hamel, JF Paquin - Synthesis, 2018 - thieme-connect.com
Monofluoroalkenes have found wide application in organic chemistry, medicinal chemistry,
and materials science. This review summarizes the most recent advances made regarding …

A vinylic Rosenmund–von Braun reaction: practical synthesis of acrylonitriles

A Pradal, G Evano - Chemical communications, 2014 - pubs.rsc.org
An efficient system based on acetone cyanohydrin and catalytic amounts of copper (I) iodide
and 1, 10-phenanthroline is reported for the cyanation of alkenyl iodides. A wide range of …

Mild and Copper‐Free Stereoselective Cyanation of gem‐Difluoroalkenes by Using Benzyl Nitrile as a Cyanating Reagent

J Zhang, C Xu, W Wu, S Cao - Chemistry–A European Journal, 2016 - Wiley Online Library
A novel copper‐free highly stereoselective cyanation of gem‐difluoroalkenes by using
benzyl nitrile as a cyanating reagent with the assistance of tBuOLi under air atmosphere at …

Nucleophilic Substitution of gem-Difluoroalkenes with TMSNu Promoted by Catalytic Amounts of Cs2CO3

LF Jiang, BT Ren, B Li, GY Zhang, Y Peng… - The Journal of …, 2019 - ACS Publications
The efficient and practical nucleophilic cyanation and trifluoromethylation with appropriate
trimethylsilyl nucleophiles were developed. Catalytic amounts of cheap and nontoxic …

Ionic liquids as a reusable media for copper catalysis. Green access to alkenes using catalytic olefination reaction

VM Muzalevskiy, AV Shastin, NG Shikhaliev… - Tetrahedron, 2016 - Elsevier
It was demonstrated that ionic liquids are superb recyclable media for copper catalyzed
reactions using catalytic olefination reaction as an example. As a result a novel green …

Stereoselective synthesis of α-fluoroacrylonitriles via organocatalytic cyanation of gem-difluoroalkenes and TMSCN

YC Ma, Y Zhang, CZ Gu, GF Du, L He - New Journal of Chemistry, 2019 - pubs.rsc.org
An organocatalytic cyanation reaction of gem-difluoroalkenes was developed. Under the
catalysis of 10 mol% DBU, gem-difluoroalkenes undergo a nucleophilic addition-β …

[图书][B] Copper-catalyzed, Oxidative Sp2 CH Cyanation: Facile Synthesis of Aromatic Carbonitriles

JQ Liu, BY Hao, H Zou, WH Zhang, XZ Chen - 2014 - arkat-usa.org
Abstract Cu (OAc) 2-catalyzed regioselective oxidative CH cyanation of two different types of
aromatics was described, providing facile access to functionalized heterocycles in good …

Fonctionnalisation d'alcènes fluorés par des groupements hétéroatomiques en position géminée

S Morand - 2022 - theses.hal.science
Les alcènes fluorés sont des composés très importants pour la synthèse de matériaux ou de
molécules bioactives. De plus les monofluoroalcènes et les trifluorométhylalcènes sont …

Palladium-Catalyzed Cross-Coupling of Gem-Bromofluoroalkenes with Alkylboronic Acids for the Synthesis of Alkylated Monofluoroalkenes

L Chausset-Boissarie, N Cheval, C Rolando - Molecules, 2020 - mdpi.com
Monofluoroalkenes are versatile fluorinated synthons in organic synthesis, medicinal
chemistry and materials science. In light of the importance of alkyl-substituted …

Building block synthesis of predominantly (E) symmetrical and unsymmetrical 1, 2-difluorostilbenes from 1, 2-dibromo-1, 2-difluoroethene

S Eddarir, M Kajjout, C Rolando - Tetrahedron, 2013 - Elsevier
An efficient synthesis of predominantly (E) symmetrical or unsymmetrical 1, 2-
difluorostilbenes based on the Suzuki–Miyaura palladium-catalyzed cross-coupling reaction …