Alkoxy radicals are highly reactive species that have long been recognized as versatile
intermediates in organic synthesis. However, their development has long been impeded due …

For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …

The chemical activation of water would allow this earth-abundant resource to be transferred
into value-added compounds, and is a topic of keen interest in energy research,. Here, we …

We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

The photoactivation of electron donor‐acceptor complexes has emerged as a sustainable,
selective and versatile strategy for the generation of radical species. Electron donor …

Phosphorus-based organocatalysis encompasses several subfields that have undergone
rapid growth in recent years. This Outlook gives an overview of its various aspects. In …

A growing number of organopnictogen redox catalytic methods have emerged—especially
within the past 10 years—that leverage the plentiful reversible two-electron redox chemistry …

As alcohols are ubiquitous throughout chemical science, this functional group represents a
highly attractive starting material for forging new C–C bonds. Here, we demonstrate that the …

Water, as a green reaction medium, is safe, non-toxic, and rich in reserves on Earth, while
visible light represents a renewable, clean, and abundant energy source. Organic …

Photoredox catalysis (PRC) has gained enormous and wide-ranging interest in recent years
but has also been subject to significant mechanistic uncertainty, even controversy. To …