Ligands for f-element extraction used in the nuclear fuel cycle

A Leoncini, J Huskens, W Verboom - Chemical Society Reviews, 2017 - pubs.rsc.org
Liquid–liquid extraction is the major technique being applied for the partitioning of f-
elements from nuclear waste. In this review, the recent developments in ligand design …

Functionalization of mesoporous materials for lanthanide and actinide extraction

J Florek, S Giret, E Juère, D Lariviere, F Kleitz - Dalton Transactions, 2016 - pubs.rsc.org
Among the energy sources currently available that could address our insatiable appetite for
energy and minimize our CO2 emission, solar, wind, and nuclear energy currently occupy …

Actinide ion extraction using room temperature ionic liquids: opportunities and challenges for nuclear fuel cycle applications

PK Mohapatra - Dalton Transactions, 2017 - pubs.rsc.org
Studies on the extraction of actinide ions from radioactive feeds have great relevance in
nuclear fuel cycle activities, mainly in the back end processes focused on reprocessing and …

Coordination chemistry of f-block metal ions with ligands bearing bio-relevant functional groups

L Götzke, G Schaper, J März, P Kaden… - Coordination Chemistry …, 2019 - Elsevier
Over recent decades there has been a great deal of interest and associated research into
aspects of the f-block (lanthanide and actinide) metal chemistry of naturally-occurring …

Ionic liquids for TRansUranic Extraction (TRUEX)—Recent developments in nuclear waste management: A review

NK Gupta - Journal of Molecular Liquids, 2018 - Elsevier
Room temperature ionic liquids (RTILs) are considered as a replacement of molecular
diluents in the extraction of metal ions from an aqueous phase. Owing to their good radiolytic …

Experimental and Theoretical Investigation on the Extractive Mass Transfer of Eu3+ Ions Using Novel Amide Ligands in 1-Hexyl-3-methylimidazolium Bis …

A Ghosh, A Pandey, A Sengupta, V Kathirvelu… - Inorganic …, 2023 - ACS Publications
Novel amide ligands in the ionic liquid (1-hexyl-3-methylimidazolium bis
(trifluoromethylsulfonyl) imide) were utilized for the liquid–liquid biphasic mass transfer of …

Benzene-centered tripodal diglycolamides: synthesis, metal ion extraction, luminescence spectroscopy, and DFT studies

A Leoncini, SA Ansari, PK Mohapatra, A Boda… - Dalton …, 2017 - pubs.rsc.org
Three benzene-centered tripodal diglycolamides (Bz-T-DGAs) were synthesized and
evaluated for actinide, lanthanide, and fission product ion extraction. 1, 3, 5-Triethylbenzene …

Selective separation and coordination of europium (III) and americium (III) by bisdiglycolamide ligands: solvent extraction, spectroscopy, and DFT calculations

P Ren, C Wang, W Tao, X Yang, S Yang… - Inorganic …, 2020 - ACS Publications
Diglycolamide-based ligands have recently received increased attention due to their
outstanding affinity for trivalent actinides and lanthanides. The structure optimization of the …

Sequestration of actinides by an extraction chromatography resin containing a triaza-9-crown-3 functionalized diglycolamide

P Banerjee, SA Ansari, PK Mohapatra… - Industrial & …, 2023 - ACS Publications
We prepared a new extraction chromatography resin by coating a diglycolamide (DGA)
ligand having three DGA moieties tethered to a triaza-9-crown-3 scaffold (TAM-3-DGA) on …

Unprecedented Inversion of Selectivity and Extraordinary Difference in the Complexation of Trivalent f Elements by Diastereomers of a Methylated Diglycolamide

A Wilden, PM Kowalski, L Klaß, B Kraus… - … A European Journal, 2019 - Wiley Online Library
When considering f elements, solvent extraction is primarily used for the removal of
lanthanides from ore and their recycling, as well as for the separation of actinides from used …