First-row transition metal (de) hydrogenation catalysis based on functional pincer ligands

L Alig, M Fritz, S Schneider - Chemical reviews, 2018 - ACS Publications
The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

Distortion pathways of transition metal coordination polyhedra induced by chelating topology

S Alvarez - Chemical Reviews, 2015 - ACS Publications
A continuous shape measures analysis of the coordination polyhedra of a host of transition
metal complexes with bi-and multidentate ligands discloses the distortion pathway …

A low-spin Fe(iii) complex with 100-ps ligand-to-metal charge transfer photoluminescence

P Chábera, Y Liu, O Prakash, E Thyrhaug, AE Nahhas… - Nature, 2017 - nature.com
Transition-metal complexes are used as photosensitizers, in light-emitting diodes, for
biosensing and in photocatalysis. A key feature in these applications is excitation from the …

Metal–Ligand Cooperativity via Exchange Coupling Promotes Iron- Catalyzed Electrochemical CO2 Reduction at Low Overpotentials

JS Derrick, M Loipersberger, R Chatterjee… - Journal of the …, 2020 - ACS Publications
Biological and heterogeneous catalysts for the electrochemical CO2 reduction reaction
(CO2RR) often exhibit a high degree of electronic delocalization that serves to minimize …

Bimolecular reactivity of 3d metal-centered excited states (Cr, Mn, Fe, Co)

C Förster, K Heinze - Chemical Physics Reviews, 2022 - pubs.aip.org
Metal-centered (MC) excited states (ESs) of 3d transition metal complexes (TMCs) often
possess rather low energies so that these represent the lowest energy ESs. Additionally, MC …

Insights into the excited state dynamics of Fe (II) polypyridyl complexes from variable-temperature ultrafast spectroscopy

MC Carey, SL Adelman, JK McCusker - Chemical science, 2019 - pubs.rsc.org
In an effort to better define the nature of the nuclear coordinate associated with excited state
dynamics in first-row transition metal-based chromophores, variable-temperature ultrafast …

Metal–organic layers stabilize earth-abundant metal–terpyridine diradical complexes for catalytic C–H activation

Z Lin, NC Thacker, T Sawano, T Drake, P Ji, G Lan… - Chemical …, 2018 - pubs.rsc.org
We report the synthesis of a terpyridine-based metal–organic layer (TPY-MOL) and its
metalation with CoCl2 and FeBr2 to afford CoCl2· TPY-MOL and FeBr2· TPY-MOL …

Low-valent transition metalate anions in synthesis, small molecule activation, and catalysis

VR Landaeta, TM Horsley Downie, R Wolf - Chemical Reviews, 2024 - ACS Publications
This review surveys the synthesis and reactivity of low-oxidation state metalate anions of the
d-block elements, with an emphasis on contributions reported between 2006 and 2022 …

Complexes of diamagnetic cations with radical anion ligands

IV Ershova, AV Piskunov… - Russian Chemical …, 2020 - iopscience.iop.org
Complexes of diamagnetic cations with radical anion ligands - IOPscience This site uses
cookies. By continuing to use this site you agree to our use of cookies. To find out more, see …

Interrogation of 2, 2′-bipyrimidines as low-potential two-electron electrolytes

JD Griffin, AR Pancoast, MS Sigman - Journal of the American …, 2021 - ACS Publications
As utilization of renewable energy sources continues to expand, the need for new grid
energy storage technologies such as redox flow batteries (RFBs) will be vital. Ultimately, the …