The study of enantiodiscriminations in relation to various facets of enantiomorphism
(chirality/prochirality) and/or molecular symmetry is an exciting area of modern organic …

NMR spectroscopy of oriented samples makes accessible residual anisotropic
intramolecular NMR interactions, such as chemical shift anisotropy (RCSA), dipolar coupling …

Butyrylcholinesterase (BChE) is a promising target for the treatment of later stage cognitive
decline in Alzheimer's disease. A set of pseudo-irreversible BChE inhibitors with high …

In this work, the practical/analytical potential of an L‐valine‐derived polyacetylene (PLA)
lyotropic liquid crystal (LLC) is examined to spectrally discriminate enantiomers (racemic …

Identifying and understanding the role of key molecular factors involved in the orientation/
discrimination phenomena of analytes in polymer-based chiral liquid crystals (CLCs) are …

Liquid crystals can partake in enantioseparations in several different ways. Enantiomeric
purity of chiral liquid crystals as analytes is often determined using enantioselective liquid or …

Lyotropic liquid crystalline (LLC) phases of polyglutamic acid derivatives, such as poly‐γ‐
benzyl‐l‐glutamate, are suitable alignment media for organic structure elucidation by NMR …

Despite its low natural abundance, deuterium NMR spectroscopy in weakly oriented (chiral)
solvents gives easy access to deuterium residual quadrupolar couplings (2H‐RQCs). These …

Herein, we report the preparation of lyotropic liquid crystalline (LLC) phases of poly-β-benzyl-
l-aspartate (PBLA), a polymer that has not been known to form LLC phases before …

We explore and report for the first time the use of 1H saturation transfer difference NMR
experiments (STD‐NMR) in weakly aligning chiral anisotropic media to identify the hydrogen …