Single-atom alloy catalysis

RT Hannagan, G Giannakakis… - Chemical …, 2020 - ACS Publications
Single-atom alloys (SAAs) play an increasingly significant role in the field of single-site
catalysis and are typically composed of catalytically active elements atomically dispersed in …

Characterisation of gold catalysts

A Villa, N Dimitratos, CE Chan-Thaw… - Chemical Society …, 2016 - pubs.rsc.org
Au-based catalysts have established a new important field of catalysis, revealing specific
properties in terms of both high activity and selectivity for many reactions. However, the …

Unlocking synergy in bimetallic catalysts by core–shell design

JES van der Hoeven, J Jelic, LA Olthof, G Totarella… - Nature materials, 2021 - nature.com
Extending the toolbox from mono-to bimetallic catalysts is key in realizing efficient chemical
processes. Traditionally, the performance of bimetallic catalysts featuring one active and one …

Effects of ensembles, ligand, and strain on adsorbate binding to alloy surfaces

H Li, K Shin, G Henkelman - The Journal of chemical physics, 2018 - pubs.aip.org
Alloying elements with strong and weak adsorption properties can produce a catalyst with
optimally tuned adsorbate binding. A full understanding of this alloying effect, however, is …

Controlling hydrogen activation, spillover, and desorption with Pd–Au single-atom alloys

FR Lucci, MT Darby, MFG Mattera… - The journal of …, 2016 - ACS Publications
Key descriptors in hydrogenation catalysis are the nature of the active sites for H2 activation
and the adsorption strength of H atoms to the surface. Using atomically resolved model …

Selective hydrogen production from formic acid decomposition on Pd–Au bimetallic surfaces

WY Yu, GM Mullen, DW Flaherty… - Journal of the American …, 2014 - ACS Publications
Pd–Au catalysts have shown exceptional performance for selective hydrogen production via
HCOOH decomposition, a promising alternative to solve issues associated with hydrogen …

Controllable Fabrication of PdO‐PdAu Ternary Hollow Shells: Synergistic Acceleration of H2‐Sensing Speed via Morphology Regulation and Electronic Structure …

Q Li, S Yang, X Lu, T Wang, X Zhang, Y Fu, W Qi - Small, 2022 - Wiley Online Library
Designing ultrafast H2 sensors is of particular importance for practical applications of
hydrogen energy but still quite challenging. Herein, PdO decorated PdAu ternary hollow …

Enhancing catalytic performance of dilute metal alloy nanomaterials

M Luneau, E Guan, W Chen, AC Foucher… - Communications …, 2020 - nature.com
Dilute alloys are promising materials for sustainable chemical production; however, their
composition and structure affect their performance. Herein, a comprehensive study of the …

Entropic control of HD exchange rates over dilute Pd-in-Au alloy nanoparticle catalysts

JES van der Hoeven, HT Ngan, A Taylor… - ACS …, 2021 - ACS Publications
Dilute Pd-in-Au alloy catalysts are promising materials for selective hydrogenation catalysis.
Extensive surface science studies have contributed mechanistic insight on the energetic …

Ethanol decomposition on Pd–Au alloy catalysts

H Li, EJ Evans Jr, CB Mullins… - The Journal of Physical …, 2018 - ACS Publications
The mechanisms of ethanol (EtOH) decomposition via C–C or C–O bond cleavage on alloy
surfaces are currently not well understood. In this study, we model EtOH decomposition on …