Chromium Ethylene Tri-/Tetramerization Catalysts Supported by Iminophosphine Ligands

X Zhao, J Wang, D Liu, W Kong, J Zhang - ACS omega, 2023 - ACS Publications
A new class of highly active ethylene tri-/tetramerization chromium catalysts supported by
iminophosphine ligands has been studied. The impact of electronic and steric changes of …

A Comparison of β–Phenyl Elimination in Nickel and Palladium Alkyl Complexes: A Potentially Relevant Process in the Mizoroki–Heck Reaction

JA López, DA Cabo, P Palma, J Cámpora - Inorganics, 2024 - mdpi.com
There is currently much interest in avoiding precious metals in catalysis. The development of
nickel catalysts to replace palladium in the Mizoroki–Heck reaction is a relevant case in this …

DFT study on the [4+ 4] domino cycloaddition of ynones with benzylidenepyrazolones to access eight-membered cyclic ethers: effects of DBU vs. Et 3 N

B Yuan, H Zhou, Y Yu, X Guo, Y Zhao… - New Journal of …, 2021 - pubs.rsc.org
The mechanisms of [4+ 4] domino cycloaddition of ynones with benzylidenepyrazolones to
access highly substituted eight-membered cyclic ethers are studied to explore the effects of …

Tertiary phosphines: preparation

EI Musina, AS Balueva, AA Karasik - 2022 - books.rsc.org
This chapter covers the literature published during 2020 relating to the synthesis of tertiary
phosphines. Although it has been necessary to continue to be selective in the choice of …

Synthetic investigations of low-coordinate (N-phosphino-amidinate) nickel chemistry: agostic alkyl complexes and benzene insertion into Ni–H

CM Macaulay, M Samolia, MJ Ferguson… - Dalton …, 2020 - pubs.rsc.org
Treatment of (PN) NiX (X= NHdipp or OtBu; PN= N-phosphinoamidinate ligand) with
Me2PhSiH in benzene solvent afforded the crystallographically characterized, antifacial …

Nickel-Carbon σ-Bonded Complexes

CL Wagner, T Diao - … Organometallic Chemistry IV: Volume 1 …, 2022 - nyuscholars.nyu.edu
This chapter documents nickel aryl and alkyl complexes. The complexes are organized by
their supporting ligands such as tridentate, bidentate and monodentate ligands. Pincer …

Quinquevalent phosphorus acids

P Bałczewski, K Owsianik - 2024 - books.rsc.org
This chapter covers scientific contributions in quinquevalent organo-phosphorus chemistry
published in the literature in 2021. The review is not comprehensive but shows the most …

[引用][C] New Perspective in the Ni-Catalyzed Heck Reaction: The Role of Deprotonable PN Ligands to Assist the β-Hydride Elimination Stage.

TG Santiago, P Palma, E Álvarez, J Cámpora