In this work, a residual entropy value of 6/10 of the way between the critical point and a
value of− 2/3 of Boltzmann constant is shown to collapse the scaled viscosity for the family of …

A linear relationship between the logarithms of solute dissociation constants, log (K), and the
density of water, log (ρ H 2 O), has empirically been demonstrated for decades and raised …

Supercritical carbon dioxide (scCO2) mixtures are essential for many industrial applications.
However, the knowledge of their thermophysical properties in the extended critical region is …

The present study reports a systematic analysis of a wide variety of structural,
thermodynamic, and dynamic properties of supercritical water along the near-critical …

For a multi-component hydrocarbon mixture under supercritical conditions, especially for
fuels injected into compression ignition engines, the mechanism for the transition of the …

We model, via classical molecular dynamics simulations, the plastic phase of ice VII across a
wide range of the phase diagram of interest for planetary investigations. Although structural …

According to textbooks, no physical observable can be discerned allowing to distinguish a
liquid from a gas beyond the critical point. Yet, several proposals have been put forward …

Using molecular dynamics simulations in combination with the two-phase thermodynamic
model, we reveal novel characteristic fingerprints of the crossing of the Frenkel and melting …

We have performed a neutron scattering experiment on supercritical fluid nitrogen at 160 K
(1.27 TC) over a wide pressure range (7.8 MPa/0.260 g/mL–125 MPa/0.805 g/mL). This has …

Examining the physical properties of materials-particularly of toxic liquids-under a wide
range of thermodynamic states is a challenging problem due to the extreme conditions the …