Organocatalysis in inert C–H bond functionalization

Y Qin, L Zhu, S Luo - Chemical reviews, 2017 - ACS Publications
As two coexisting and fast-growing research fields in modern synthetic chemistry, the
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …

C H Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

J Yamaguchi, AD Yamaguchi… - Angewandte Chemie …, 2012 - Wiley Online Library
The direct functionalization of C H bonds in organic compounds has recently emerged as a
powerful and ideal method for the formation of carbon–carbon and carbon–heteroatom …

Towards mild metal-catalyzed C–H bond activation

J Wencel-Delord, T Dröge, F Liu… - Chemical Society Reviews, 2011 - pubs.rsc.org
Functionalizing traditionally inert carbon–hydrogen bonds represents a powerful
transformation in organic synthesis, providing new entries to valuable structural motifs and …

Bond formations between two nucleophiles: transition metal catalyzed oxidative cross-coupling reactions

C Liu, H Zhang, W Shi, A Lei - Chemical Reviews, 2011 - ACS Publications
In chemistry, a nucleophile is a molecule or ion with a lone pair of electrons. It donates both
bonding electrons to its reaction partner (the electrophile) when forming a chemical bond. 1 …

Functionalization of Organic Molecules by Transition‐Metal‐Catalyzed C(sp3)H Activation

R Jazzar, J Hitce, A Renaudat… - … A European Journal, 2010 - Wiley Online Library
Transition‐metal‐catalyzed C H activation has recently emerged as a powerful tool for the
functionalization of organic molecules. While many efforts have focused on the …

Funktionalisierung von C‐H‐Bindungen: neue Synthesemethoden für Naturstoffe und Pharmazeutika

J Yamaguchi, AD Yamaguchi, K Itami - Angewandte Chemie, 2012 - Wiley Online Library
Die direkte Funktionalisierung von C‐H‐Bindungen in organischen Molekülen hat sich in
jüngster Zeit zu einer wirksamen und idealen Methode entwickelt, mit der Kohlenstoff …

The emergence of sulfoxides as efficient ligands in transition metal catalysis

G Sipos, EE Drinkel, R Dorta - Chemical Society Reviews, 2015 - pubs.rsc.org
Sulfoxides are capable of forming stable complexes with transition metals and there have
been many comprehensive studies into their binding properties. However, the use of …

Pd-catalyzed oxidative coupling with organometallic reagents via C–H activation

CL Sun, BJ Li, ZJ Shi - Chemical communications, 2010 - pubs.rsc.org
Direct selective palladium catalyzed C–H functionalization has become a highly attractive
strategy in organic synthesis and represents a highly desirable goal. Compared with cross …

C− H coupling reactions directed by sulfoxides: teaching an old functional group new tricks

AP Pulis, DJ Procter - Angewandte Chemie International …, 2016 - Wiley Online Library
Sulfoxides are classical functional groups for directing the stoichiometric metalation and
functionalization of C− H bonds. In recent times, sulfoxides have been given a new lease on …

Transition-metal catalyzed oxidative cross-coupling reactions to form C–C bonds involving organometallic reagents as nucleophiles

W Shi, C Liu, A Lei - Chemical Society Reviews, 2011 - pubs.rsc.org
Transition-metal-catalyzed coupling reactions have become a versatile tool for chemical
bond formation. From the variation of the coupling partners, coupling reactions can be …