Although significant efforts have been made for the direct syngas conversion to ethanol,
ethanol yield remains low. Herein, we studied syngas conversion on the Rh/TiO2 catalysts …

The reactivity of the surface species present over a 2% Pt/CeO2 catalyst during the reverse
water-gas-shift (RWGS) reaction was investigated by a detailed operando spectrokinetic …

The study of catalytic materials is commonly approached from three standpoints; catalyst
preparation, catalyst characterisation and ultimately the evaluation of catalytic performance …

Steady-state isotopic-transient kinetic analysis (SSITKA) is a very useful technique for the
kinetic study of heterogeneous catalytic reactions. Initially developed by Happel, 1 Bennett …

The interaction of CO2 and H2/CO2 with pure β-Ga2O3 and Pd/β-Ga2O3 (1 wt% Pd) was
studied by temperature-programmed reaction, between 323 K and 723 K at 0.1 MPa, using …

The effect of H2 partial pressure in a wide range (P H2= 0.12–0.6 bar, or H2/CO gas ratio of
2–10; P CO= 0.06 bar) on important kinetic parameters of the methanation reaction at 230° …

Experiments in the transient regime are now widely used in mechanistic studies of
heterogeneous catalysis. They permit the quantitative determination of the surface …

The hydrogenation of CO and CO2over Rh/SiO2have been investigated for the purpose of
identifying the similarities and differences between these two reaction systems. In …

Cu-based catalysts have been widely used and produced promising results for ethanol
formation from syngas; understanding the underlying mechanism at the molecular level is …

Mechanism of C2+ oxygenate synthesis on Rh catalysts Page 1 Mechanism of C2+ oxygenate
synthesis on Rh catalysts Steven SC Chuang*, Robert W. Stevens, Jr., and Rajesh Khatri …