Charged carbon nanomaterials: redox chemistries of fullerenes, carbon nanotubes, and graphenes

AJ Clancy, MK Bayazit, SA Hodge, NT Skipper… - Chemical …, 2018 - ACS Publications
Since the discovery of buckminsterfullerene over 30 years ago, sp2-hybridised carbon
nanomaterials (including fullerenes, carbon nanotubes, and graphene) have stimulated new …

Advances in carbon nanotube n-type doping: Methods, analysis and applications

L Brownlie, J Shapter - Carbon, 2018 - Elsevier
Great advances in semiconductor technologies continue to be made with the demand for
cheap, non-toxic, easily processed and environmentally friendly technologies on the rise …

Advanced carbon nanotubes functionalization

A Setaro - Journal of Physics: Condensed Matter, 2017 - iopscience.iop.org
Similar to graphene, carbon nanotubes are materials made of pure carbon in its sp 2 form.
Their extended conjugated π-network provides them with remarkable quantum …

Fundamental insights into the reductive covalent cross-linking of single-walled carbon nanotubes

M Schirowski, G Abellán, E Nuin… - Journal of the …, 2018 - ACS Publications
Single-walled carbon nanotubes (SWCNT) have been covalently cross-linked via a
reductive functionalization pathway, utilizing negatively charged carbon nanotubides (KC4) …

Diameter dependence of the defect-induced Raman modes in functionalized carbon nanotubes

J Laudenbach, D Schmid, F Herziger, F Hennrich… - Carbon, 2017 - Elsevier
Covalent functionalization of single-walled carbon nanotubes typically leads to an intensity
increase of the defect-induced Raman mode (D mode). A large intensity ratio of the D and G …

Understanding the electron-doping mechanism in potassium-intercalated single-walled carbon nanotubes

C Kröckel, MR Preciado-Rivas… - Journal of the …, 2020 - ACS Publications
Single-walled carbon nanotubes (SWCNTs) can be doped with potassium, similar to
graphite, leading to intercalation compounds. These binary systems exhibit a clear metallic …

Controlling the Degree of Functionalization: In‐Depth Quantification and Side‐Product Analysis of Diazonium Chemistry on SWCNTs

M Schirowski, F Hauke, A Hirsch - Chemistry–A European …, 2019 - Wiley Online Library
We present an in‐depth qualitative and quantitative analysis of a reaction between 4‐
iodobenzenediazonium tetrafluoroborate and single‐walled carbon nanotubes (SWCNTs) …

Measurement of a Diameter-Dependent Charge Transfer in Solution-Phase Carbon Nanotubes Using Raman Spectroscopy

SM Williams, RA Pinnick, L Sun… - The Journal of …, 2023 - ACS Publications
Superacids such as chlorosulfonic acid (CSA) and oleum spontaneously dissolve carbon
nanotubes (CNT) in high concentrations without damaging their structure. Despite …

Trajectory of the selective dissolution of charged single-walled carbon nanotubes

DJ Buckley, SA Hodge, M De Marco, S Hu… - The Journal of …, 2017 - ACS Publications
Single-walled carbon nanotubes (SWCNTs) are typically produced as a mixture of different
lengths and electronic types. Methods for sorting these as-produced mixtures typically …

Reductive diazotation of carbon nanotubes: an experimental and theoretical selectivity study

M Schirowski, C Tyborski, J Maultzsch, F Hauke… - Chemical …, 2019 - pubs.rsc.org
The reaction of neutral single-walled carbon nanotubes (SWCNTs) with diazonium salts
proceeds with a high selectivity towards metallic carbon nanotube species; this reaction is …