Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from
simple, readily available feedstocks have become a cornerstone of modern synthetic …

Catalytic transformations involving metal carbenes are considered one of the most important
aspects of homogeneous transition metal catalysis. Recently, gold-catalyzed generation of …

Abstract Transition-metal-catalysed, non-enzymatic transformations of C–H and C= C bonds
to C–N bonds through nitrene transfer (NT) are powerful synthetic tools to prepare valuable …

A catalytic system for intermolecular benzylic C (sp3)–H amination is developed utilizing 1,
2, 3, 4-tetrazole as a nitrene precursor via iron catalysis. This method enables direct …

Direct C–H bond functionalization catalyzed by non-precious transition metals is an
attractive strategy in synthetic chemistry. Compared with the precious metals rhodium …

Transition-metal-catalyzed direct C–N bond formation via metal nitrenoid (metal
imido/nitrene complexes) transfer reactions such as C–H bond amination/amidation and …

Allylic C–H amination is currently accomplished with (sulfon) amides or carbamates. Here
we show the first allylic amination that can directly afford alkyl allylamines, enabled by the …

Catalytic C–H amination reactions enable direct functionalization of non-activated C (sp3)–H
bonds with high levels of regio-, chemo-and stereoselectivity. As a powerful tool to unlock …

Chiral benzylic amines are privileged motifs in pharmacologically active molecules.
Intramolecular enantioselective radical C (sp3)− H functionalization by hydrogen‐atom …

Direct conversion of hydrocarbons into amines represents an important and atom-economic
goal in chemistry for decades. However, intermolecular cross-coupling of terminal alkenes …