Readily accessible and shelf-stable 1, 2, 3-triazole and its analogues such as pyridotriazole,
triazoloindole, benzotriazole, and thiadiazole exist in equilibrium with their ring-opened …

Metal-stabilized carbenes derived from diazo compounds have become broadly useful
reactive intermediates for organic synthesis. This tutorial review will describe the recent …

Metal carbenes usually possess versatile reactivities that are controlled by the presence of
both the metals and the ligands. Diazo compounds are commonly used for the generation of …

Heterocyclic scaffolds are commonly found in numerous biologically active molecules,
therapeutic agents, and agrochemicals. To probe chemical space around heterocycles …

In recent years, α‐imino rhodium carbene complexes derived by ring‐opening of N‐sulfonyl‐
1, 2, 3‐triazoles have attracted much attention from organic chemists. Many transformations …

Natural products have long served as a rich resource for drug discovery in the treatment of
illnesses and chronic diseases. Among many families exhibiting fascinating structural …

The prodiginine family of bacterial alkaloids is a diverse set of heterocyclic natural products
that have likely been known to man since antiquity. In more recent times, these alkaloids …

Suitably substituted electron-deficient 1, 2, 3-triazoles exist in equilibrium with their ring-
opened α-diazoimine tautomers. This phenomenon was used to facilitate the generation of …

A highly efficient and practical method for incorporation of the arylmethylpyridyl moiety into
diverse molecules has been developed. This method features the transition metal-free light …

Rhodium (II) azavinyl carbenes, conveniently generated from 1-sulfonyl-1, 2, 3-triazoles,
undergo a facile, mild, and convergent formal 1, 3-insertion into N–H and O–H bonds of …