The aluminyl anion: a new generation of aluminium nucleophile

J Hicks, P Vasko, JM Goicoechea… - Angewandte …, 2021 - Wiley Online Library
Trivalent aluminium compounds are well known for their reactivity as Lewis
acids/electrophiles, a feature that is exploited in many pharmaceutical, industrial and …

Recent advances in low oxidation state aluminium chemistry

K Hobson, CJ Carmalt, C Bakewell - Chemical Science, 2020 - pubs.rsc.org
The synthesis and isolation of novel low oxidation state aluminium (Al) compounds has seen
relatively slow progress over the 30 years since such species were first isolated. This is …

The unique β-diketiminate ligand in aluminum (I) and gallium (I) chemistry

M Zhong, S Sinhababu, HW Roesky - Dalton Transactions, 2020 - pubs.rsc.org
Over the past few decades, β-diketiminate ligands have been widely used in coordination
chemistry and are capable of stabilizing various metal complexes in multiple oxidation …

Probing the extremes of covalency in M− Al bonds: lithium and zinc aluminyl compounds

MMD Roy, J Hicks, P Vasko, A Heilmann… - Angewandte …, 2021 - Wiley Online Library
Synthetic routes to lithium, magnesium, and zinc aluminyl complexes are reported, allowing
for the first structural characterization of an unsupported lithium–aluminium bond …

Main-group metal complexes of α-diimine ligands: structure, bonding and reactivity

R Zhang, Y Wang, Y Zhao, C Redshaw… - Dalton …, 2021 - pubs.rsc.org
α-Diimine ligands, in particular 1, 4-diazabutadiene (dad) and bis (iminoacenaphthene)(
bian) derivatives, have been widely used for coordination with various metals, including …

Facile fabrication of boron and nitrogen co-doped carbon dots for “ON–OFF–ON” fluorescence sensing of Al 3+ and F− ions in water samples

YS Alqahtani, AM Mahmoud, MH Mahnashi, R Ali… - RSC …, 2023 - pubs.rsc.org
Water contamination with harmful ions has grown to be a significant environmental issue on
a global scale. Therefore, the fabrication of simple, cost-effective, and reliable sensors is …

Nitrogen and boron co-doped carbon dots as a novel fluorescent probe for fluorogenic sensing of Ce4+ and ratiometric detection of Al3+

X Li, L Zhao, Y Wu, A Zhou, X Jiang, Y Zhan… - Spectrochimica Acta Part …, 2022 - Elsevier
Carbon dots have been widely focused on the field of metal ion detection due to their
excellent optical property. Herein, novel orange fluorescent nitrogen and boron co-doped …

Group 13 monohalides [AX (A= B, Al, Ga and In; X= Halogens)] as alternative ligands for carbonyl in organometallics: Electronic structure and bonding analysis

F Paularokiadoss, TC Jeyakumar, R Thomas… - Computational and …, 2022 - Elsevier
Iron pentacarbonyl complexes have received a lot of interest because of their unique
bonding nature and trigonal bipyramidal structure. When one carbonyl in each of the axial …

Reactions of an Aluminum (I) Reagent with 1, 2-, 1, 3-, and 1, 5-Dienes: Dearomatization, Reversibility, and a Pericyclic Mechanism

C Bakewell, M Garçon, RY Kong, L O'Hare… - Inorganic …, 2020 - ACS Publications
Addition of the aluminum (I) reagent [{(ArNCMe) 2CH} Al](Ar= 2, 6-di-iso-propylphenyl) to a
series of cyclic and acyclic 1, 2-, 1, 3-, and 1, 5-dienes is reported. In the case of 1, 3-dienes …

A Tetraorganyl-Alumaborane with An Al–B σ-Bond and Two Adjacent Lewis-Acidic Centers

S Kurumada, M Yamashita - Journal of the American Chemical …, 2022 - ACS Publications
A tetraorganyl-alumaborane (3) that contains an Al–B bond and twisted Al and B planes was
synthesized and structurally characterized. UV–vis absorption spectroscopy …