Critical review of advances in engineering nanomaterial adsorbents for metal removal and recovery from water: mechanism identification and engineering design

J Luo, D Yu, KD Hristovski, K Fu, Y Shen… - Environmental …, 2021 - ACS Publications
Nanomaterial adsorbents (NAs) have shown promise to efficiently remove toxic metals from
water, yet their practical use remains challenging. Limited understanding of adsorption …

Facet-dependent contaminant removal properties of hematite nanocrystals and their environmental implications

X Huang, X Hou, X Zhang, KM Rosso… - Environmental Science …, 2018 - pubs.rsc.org
Hematite nanocrystals are ubiquitous in natural environments, and because of their strong
sorption properties these particles can influence the mobility and fate of toxic elements such …

Facet-dependent photodegradation of methylene blue by hematite nanoplates in visible light

M Zong, D Song, X Zhang, X Huang, X Lu… - Environmental …, 2020 - ACS Publications
The expression of specific crystal facets in different nanostructures is known to play a vital
role in determining the sensitivity toward the photodegradation of organics, which can …

Mechanistic study for antimony adsorption and precipitation on hematite facets

L Yan, T Chan, C Jing - Environmental Science & Technology, 2022 - ACS Publications
Heterogeneous reactions at the mineral–water interface are of paramount importance in
controlling the transport of contaminants. Herein, antimony (Sb) adsorption and subsequent …

Arsenic adsorption on hematite facets: spectroscopy and DFT study

L Yan, T Chan, C Jing - Environmental Science: Nano, 2020 - pubs.rsc.org
Hematite (Fe2O3) nanoparticles are omnipresent in nature and of great importance in
controlling the environmental fate of arsenic (As). Fe2O3 facets exhibit a significant effect on …

Enhanced adsorption and photocatalytic degradation of perfluorooctanoic acid in water using iron (hydr) oxides/carbon sphere composite

T Xu, H Ji, Y Gu, T Tong, Y Xia, L Zhang… - Chemical Engineering …, 2020 - Elsevier
Perfluorooctanoic acid (PFOA) has been widely detected in aquatic systems. Yet, cost-
effective technologies for degrading PFAS have been lacking. We prepared and tested an …

Interplay between facets and defects during the dissociative and molecular adsorption of water on metal oxide surfaces

N Lahiri, D Song, X Zhang, X Huang… - Journal of the …, 2023 - ACS Publications
Surface terminations and defects play a central role in determining how water interacts with
metal oxides, thereby setting important properties of the interface that govern reactivity such …

Toward informed design of nanomaterials: a mechanistic analysis of structure–property–function relationships for faceted nanoscale metal oxides

HE Rudel, MKM Lane, CL Muhich, JB Zimmerman - ACS nano, 2020 - ACS Publications
Nanoscale metal oxides (NMOs) have found wide-scale applicability in a variety of
environmental fields, particularly catalysis, gas sensing, and sorption. Facet engineering, or …

Structural incorporation of manganese into goethite and its enhancement of Pb (II) adsorption

H Liu, X Lu, M Li, L Zhang, C Pan… - … science & technology, 2018 - ACS Publications
Natural goethite (α-FeOOH) commonly accommodates various metal elements by
substituting for Fe, which greatly alters the surface reactivity of goethite. This study discloses …

Novel insight into the competitive adsorption behaviors of As (V), Sb (V), and P (V) on {1 1 0} facets of Goethite: Existing form and coordination structure affinity

X Wang, Y Zhang, C Song, Z Shen, T Wang… - Chemical Engineering …, 2024 - Elsevier
Despite the geochemical prominence of As (V), Sb (V), and P (V) coexisting in an extensive
array of iron-oxide environments, the comprehension of their mobility and destiny is …