A review on the potential and limitations of recyclable thermosets for structural applications

W Post, A Susa, R Blaauw, K Molenveld… - Polymer reviews, 2020 - Taylor & Francis
The outstanding performance of conventional thermosets arising from their covalently cross-
linked networks directly results in a limited recyclability. The available commercial or close …

Polymer engineering based on reversible covalent chemistry: A promising innovative pathway towards new materials and new functionalities

ZP Zhang, MZ Rong, MQ Zhang - Progress in Polymer Science, 2018 - Elsevier
Reversible covalent polymers are able to change their bond arrangement and structure via
reversible reaction triggered by external stimuli including heating, light and pH, while …

Cleavable comonomers enable degradable, recyclable thermoset plastics

P Shieh, W Zhang, KEL Husted, SL Kristufek, B Xiong… - Nature, 2020 - nature.com
Thermosets—polymeric materials that adopt a permanent shape upon curing—have a key
role in the modern plastics and rubber industries, comprising about 20 per cent of polymeric …

Facile in situ preparation of high-performance epoxy vitrimer from renewable resources and its application in nondestructive recyclable carbon fiber composite

S Wang, S Ma, Q Li, X Xu, B Wang, W Yuan, S Zhou… - Green chemistry, 2019 - pubs.rsc.org
Epoxy resins have been widely used in several materials including carbon fiber composites;
however, they are arduous to recycle. In this study, for the first time, a Schiff base epoxy …

Degradable thermosets based on labile bonds or linkages: A review

S Ma, DC Webster - Progress in Polymer Science, 2018 - Elsevier
Compared with thermoplastic polymers, thermoset polymers are difficult to recycle because
they can not be remolded once cured and often do not decompose under mild conditions …

Control of reactions and network structures of epoxy thermosets

T Vidil, F Tournilhac, S Musso, A Robisson… - Progress in Polymer …, 2016 - Elsevier
Recent advances in macromolecular chemistry have revolutionized the way we perceive the
synthesis of polymers. Polymerization, to be modern, must be “controlled”, which usually …

Fast reprocessing of acetal covalent adaptable networks with high performance enabled by neighboring group participation

Q Li, S Ma, P Li, B Wang, Z Yu, H Feng, Y Liu… - …, 2021 - ACS Publications
Covalent adaptable networks (CANs) represent a transition material combining favorable
features of thermosets and thermoplastics. However, it is still a huge challenge to …

Bulk network polymers with dynamic B–O bonds: Healable and reprocessable materials

AP Bapat, BS Sumerlin, A Sutti - Materials Horizons, 2020 - pubs.rsc.org
The need to minimize the amount of polymeric waste entering landfills and oceans has led
to several research avenues in the field of polymer science. Particularly, the development of …

Sustainable end-of-life management of wind turbine blades: Overview of current and coming solutions

L Mishnaevsky Jr - Materials, 2021 - mdpi.com
Various scenarios of end-of-life management of wind turbine blades are reviewed.“Reactive”
strategies, designed to deal with already available, ageing turbines, installed in the 2000s …

Readily recyclable, high-performance thermosetting materials based on a lignin-derived spiro diacetal trigger

S Ma, J Wei, Z Jia, T Yu, W Yuan, Q Li… - Journal of Materials …, 2019 - pubs.rsc.org
Conventional thermosets, widely used in composites, coatings, electronic packing materials,
etc., are typically made of non-sustainable fossil resources and cannot be recycled under …