The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …

Rapidly emerging application of organometallic manganese complexes incorporating less
elaborated mono-and bidentate donor ligands in catalytic hydrogenation, transfer …

Reductive functionalization of the C= O unit in carboxylic acids, carbonic acid derivatives,
and ultimately in carbon dioxide itself is a challenging task of key importance for the …

Reductive transformations of easily available oxidized matter are at the heart of synthetic
manipulation and chemical valorization. The applications of catalytic hydrofunctionalization …

Recent developments in manganese-catalyzed reducing transformations—hydrosilylation,
hydroboration, hydrogenation, and transfer hydrogenation—are reviewed herein. Over the …

The synthesis and structures of the first SiII‐donor supported manganese (II) complexes [L1]
MnCl2,[L2] MnCl2, and [L3] 2MnCl2 are reported, bearing a pincer‐type bis (NHSi)‐pyridine …

Over the past few decades, manganese‐catalyzed hydrosilylation of C= O or C= C/C≡ C
unsaturated bonds have undergone enormous developments. In this focus review, the …

The manganese‐catalyzed hydrosilylation and hydroboration of alkenes has been
developed using a single manganese (II) precatalyst and reaction protocol. Both reactions …

Catalysis is the second largest application for V after its use as an additive to improve steel
production. Molecular complexes of vanadium (V) are particularly useful and efficient …

Hydrosilylation of alkenes is an important process in the synthesis of organosilicon
compounds in which an Si–H species is added across a carbon–carbon double bond (C …