Carbohydrate-based macromolecular biomaterials

L Su, Y Feng, K Wei, X Xu, R Liu, G Chen - Chemical Reviews, 2021 - ACS Publications
Carbohydrates are the most abundant and one of the most important biomacromolecules in
Nature. Except for energy-related compounds, carbohydrates can be roughly divided into …

From supramolecular polymers to multi-component biomaterials

OJGM Goor, SIS Hendrikse, PYW Dankers… - Chemical Society …, 2017 - pubs.rsc.org
The most striking and general property of the biological fibrous architectures in the
extracellular matrix (ECM) is the strong and directional interaction between biologically …

Supramolecular polymers–we've come full circle

T Aida, EW Meijer - Israel Journal of Chemistry, 2020 - Wiley Online Library
Since the first polymers were discovered, scientists have debated their structures. Before
Hermann Staudinger published the brilliant concept of macromolecules, polymer properties …

Future of supramolecular copolymers unveiled by reflecting on covalent copolymerization

B Adelizzi, NJ Van Zee, LNJ de Windt… - Journal of the …, 2019 - ACS Publications
Supramolecular copolymers are an emerging class of materials, and in the last years their
potential has been demonstrated on a broad scale. Implementing noncovalent polymers …

Molecular Tuning of a Benzene‐1, 3, 5‐Tricarboxamide Supramolecular Fibrous Hydrogel Enables Control over Viscoelasticity and Creates Tunable ECM‐Mimetic …

S Hafeez, AA Aldana, H Duimel, FAA Ruiter… - Advanced …, 2023 - Wiley Online Library
Traditional synthetic covalent hydrogels lack the native tissue dynamics and hierarchical
fibrous structure found in the extracellular matrix (ECM). These dynamics and fibrous …

Polymorphism in benzene-1, 3, 5-tricarboxamide supramolecular assemblies in water: a subtle trade-off between structure and dynamics

NM Matsumoto, RPM Lafleur, X Lou… - Journal of the …, 2018 - ACS Publications
In biology, polymorphism is a well-known phenomenon by which a discrete
biomacromolecule can adopt multiple specific conformations in response to its environment …

Molecular communications in complex systems of dynamic supramolecular polymers

M Crippa, C Perego, AL de Marco… - Nature Communications, 2022 - nature.com
Supramolecular polymers are composed of monomers that self-assemble non-covalently,
generating distributions of monodimensional fibres in continuous communication with each …

Classifying soft self-assembled materials via unsupervised machine learning of defects

A Gardin, C Perego, G Doni, GM Pavan - Communications Chemistry, 2022 - nature.com
Unlike molecular crystals, soft self-assembled fibers, micelles, vesicles, etc., exhibit a certain
order in the arrangement of their constitutive monomers but also high structural dynamicity …

Elucidating the ordering in self-assembled glycocalyx mimicking supramolecular copolymers in water

SIS Hendrikse, L Su, TP Hogervorst… - Journal of the …, 2019 - ACS Publications
Polysaccharides present in the glycocalyx and extracellular matrix are highly important for a
multitude of functions. Oligo-and polysaccharides-based biomaterials are being developed …

Supramolecular Double Helices from Small C3-Symmetrical Molecules Aggregated in Water

RPM Lafleur, S Herziger… - Journal of the …, 2020 - ACS Publications
Supramolecular fibers in water, micrometers long and several nanometers in width, are
among the most studied nanostructures for biomedical applications. These supramolecular …