Hydrogen spillover-bridged Volmer/Tafel processes enabling ampere-level current density alkaline hydrogen evolution reaction under low overpotential

HQ Fu, M Zhou, PF Liu, P Liu, H Yin… - Journal of the …, 2022 - ACS Publications
Water-alkaline electrolysis holds a great promise for industry-scale hydrogen production but
is hindered by the lack of enabling hydrogen evolution reaction electrocatalysts to operate at …

Chromium catalysts for selective ethylene oligomerization to 1-hexene and 1-octene: Recent results

KA Alferov, GP Belov, Y Meng - Applied Catalysis A: General, 2017 - Elsevier
The objective of this review is the analysis and comment of recent publication results (from
July 2010 until February 2017) obtained for selective ethylene oligomerization toward 1 …

Functional Short-Bite Ligands: Synthesis, Coordination Chemistry, and Applications of N-Functionalized Bis(diaryl/dialkylphosphino)amine-type Ligands

C Fliedel, A Ghisolfi, P Braunstein - Chemical reviews, 2016 - ACS Publications
The aim of this review is to highlight how the diversity generated by N-substitution in the well-
known short-bite ligand bis (diphenylphosphino) amine (DPPA) allows a fine-tuning of the …

Quantum-mechanical transition-state model combined with machine learning provides catalyst design features for selective Cr olefin oligomerization

SM Maley, DH Kwon, N Rollins, JC Stanley… - Chemical …, 2020 - pubs.rsc.org
The use of data science tools to provide the emergence of non-trivial chemical features for
catalyst design is an important goal in catalysis science. Additionally, there is currently no …

Computational transition-state design provides experimentally verified Cr (P, N) catalysts for control of ethylene trimerization and tetramerization

DH Kwon, JT Fuller III, UJ Kilgore, OL Sydora… - ACS …, 2018 - ACS Publications
Computational design of molecular homogeneous organometallic catalysts followed by
experimental realization remains a significant challenge. Here, we report the development …

Solution XANES and EXAFS analysis of active species of titanium, vanadium complex catalysts in ethylene polymerisation/dimerisation and syndiospecific styrene …

J Yi, N Nakatani, K Nomura - Dalton Transactions, 2020 - pubs.rsc.org
Mechanistic studies in homogeneous catalysis through the solution transition metal K Edge
XANES (X-ray absorption near-edge structure) and EXAFS (Extended X-ray absorption fine …

Irradiation accelerated fluoride molten salt corrosion of nickel-based UNS N10003 alloy revealed by X-ray absorption fine structure

G Lei, C Li, Z Jiang, H Huang - Corrosion Science, 2020 - Elsevier
Helium ion irradiation accelerating molten salt corrosion of nickel-based UNS N10003 alloy
was noted for severely dissolving of chromium element. X-ray absorption fine structure was …

Solution X-ray absorption spectroscopy (XAS) for analysis of catalytically active species in reactions with ethylene by homogeneous (Imido) vanadium (V) complexes …

K Nomura - Catalysts, 2019 - mdpi.com
Solution V K-edge XANES (X-ray absorption near edge structure) and EXAFS (extended X-
ray absorption fine structure) analysis of vanadium (V) complexes containing both imido …

XAS Analysis of Reactions of (Arylimido)vanadium(V) Dichloride Complexes Containing Anionic NHC That Contains a Weakly Coordinating B(C6F5)3 Moiety (WCA …

K Nomura, G Nagai, I Izawa, T Mitsudome, M Tamm… - ACS …, 2019 - ACS Publications
(Arylimido) vanadium (V) dichloride complexes containing anionic N-heterocyclic carbene
(NHC) ligands that contain weakly coordinating B (C6F5) 3 moieties (WCA-NHC) of the type …

On the mechanism of rapid metal exchange between thiolate-protected gold and gold/silver clusters: a time-resolved in situ XAFS study

B Zhang, OV Safonova, S Pollitt, G Salassa… - Physical Chemistry …, 2018 - pubs.rsc.org
The fast metal exchange reaction between Au38 and AgxAu38− x nanoclusters in solution
at− 20° C has been studied by in situ X-ray absorption spectroscopy (time resolved quick …