Wacker-type oxidation and dehydrogenation of terminal olefins using molecular oxygen as the sole oxidant without adding ligand

YF Wang, YR Gao, S Mao, YL Zhang, DD Guo… - Organic …, 2014 - ACS Publications
An efficient and economical palladium-catalyzed oxidation system has been identified. The
oxidation system, characterized by not adding ligand and using molecular oxygen as the …

Decamethylosmocene-catalyzed efficient oxidation of saturated and aromatic hydrocarbons and alcohols with hydrogen peroxide in the presence of pyridine

GB Shul'pin, MV Kirillova, YN Kozlov, LS Shul'pina… - Journal of catalysis, 2011 - Elsevier
Decamethylosmocene,(Me5C5) 2Os (1), is a pre-catalyst in a very efficient oxidation of
alkanes with hydrogen peroxide in acetonitrile at 20–60° C. The reaction proceeds with a …

[HTML][HTML] Peroxide-mediated Wacker oxidations for organic synthesis

BW Michel, MS Sigman - Aldrichimica Acta, 2011 - ncbi.nlm.nih.gov
The Wacker oxidation is a powerful synthetic transformation, which converts a terminal olefin
to a methyl ketone via palladium catalysis, traditionally employing molecular oxygen as the …

The impact of chemical treatment on optical and electrical characteristics of multipod PbSe nanocrystal films

Z Yang, M Wang, Y Shi, X Song, Z Lin… - Journal of Materials …, 2012 - pubs.rsc.org
PbSe nanocrystals with different shapes like rods, stars and multipods have recently been
synthesized successfully based on different mechanisms. By common methods like spin …

Oxone–acetone mediated Wacker-type oxidation of benzo-fused olefins

RS Phatake, CV Ramana - Tetrahedron Letters, 2015 - Elsevier
Herein we disclose a novel application of the oxone–acetone combination for the Wacker-
type oxidation of indenes and dihydronaphthalenes leading, respectively, to indan-2-ones …

Features of the Liquid-Phase Oxidation of Alkenes to Carbonyl Compounds in the Presence of Palladium Compounds

LL Gogin, EG Zhizhina - Catalysis in Industry, 2021 - Springer
Some specific features in the liquid-phase oxidation of alkenes to ketones or aldehydes in
the presence of palladium compounds (Wacker oxidation) are discussed. It is shown that …

Direct conversion of allyl arenes to aryl ethylketones via a TBHP-mediated palladium-catalyzed tandem isomerization–Wacker oxidation of terminal alkenes

JW Zhao, L Liu, SJ Xiang, Q Liu… - Organic & Biomolecular …, 2015 - pubs.rsc.org
A TBHP-mediated palladium-catalyzed tandem isomerization–Wacker oxidation of terminal
alkenes was developed. This methodology provides a new efficient and simple route for …

Ruthenium (IV) porphyrin catalyzed highly selective oxidation of internal alkenes into ketones with Cl2pyNO as terminal oxidant

ZM Wang, XL Sang, CM Che, J Chen - Tetrahedron Letters, 2014 - Elsevier
A new method for the conversion of internal alkenes into ketones without cleavage of C
double bondC bond by using dichlororuthenium (IV) meso-tetrakis (2, 6-dichlorophenyl) …

Особенности жидкофазного окисления алкенов в карбонильные соединения в присутствии соединений палладия

ЛЛ Гогин, ЕГ Жижина - Катализ в промышленности, 2021 - elibrary.ru
В настоящем обзоре обсуждаются особенности жидкофазного окисления алкенов в
кетоны или альдегиды в присутствии соединений палладия (Вакер-окисление) …

Acetaldehyde from Ethylene and Related Wacker‐Type Reactions

R Jira - Liquid Phase Aerobic Oxidation Catalysis: Industrial …, 2016 - Wiley Online Library
Stoichiometric or catalytic oxidation of olefins to carbonyl compounds by palladium
compounds, the Wacker reaction, was found after World War II. The oxidation of ethylene to …