The high gravimetric energy density and environmental benefits place hydrogen as a
promising alternative to the widely used fossil fuels, which is however impeded by the lack of …

The construction of thousands of well-defined, porous, metal–organic framework (MOF)
structures, spanning a broad range of topologies and an even broader range of pore sizes …

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Rod MOFs are metal–organic frameworks in which the metal-containing secondary building
units consist of infinite rods of linked metal-centered polyhedra. For such materials, we …

Metal–organic frameworks (MOFs) are constructed from metal ions/clusters coordinated by
organic linkers (or bridging-ligands). The hallmark of MOFs is their permanent porosity …

Oxygen is a critical gas for medical and industrial settings. Much of today's global oxygen
supply is via inefficient technologies such as cryogenic distillation, membranes or zeolites …

Over the last at least three decades, the science of porous solid materials has become one
of the most intense areas of study for chemists, physicists, and materials scientists. These …

The decreasing fossil fuel supply and climate change caused by carbon dioxide emission
have spurred an initiative to develop alternative fuels. Hydrogen is one of the most …

Crystal engineering of coordination polymers with structure-based properties is of great
current interest.(1) Coordination polymers are a new kind of molecular materials which have …

The development in the field MOF materials is moving from the discovery of new structures
toward applications of the most promising materials. In most cases, specialized applications …