High-throughput thermodynamic analysis of the CVD of SiC from the SiCl4-CH4-H2 system

W Huang, J Wang, X Qingfang, M Yang, K Liu… - Surface and Coatings …, 2023 - Elsevier
A high-throughput thermodynamic analysis based on the CALPHAD approach is employed
in this study to gain insights into the chemical vapor deposition (CVD) of SiC from the SiCl 4 …

Computational thermodynamic study on CVD of silicon oxynitride films from Si–O–N–H and Si–O–N–H–Cl systems

W Huang, J Wang, Q Xu, M Yang, K Liu, J Peng… - Ceramics …, 2024 - Elsevier
High-throughput thermodynamic analysis of chemical vapor deposition of silicon oxynitride
films from the Si–O–N–H and Si–O–N–H–Cl systems are performed based on the …

Growth mechanism of SiC chemical vapor deposition: adsorption and surface reactions of active Si species

P Sukkaew, E Kalered, E Janzén… - The Journal of …, 2018 - ACS Publications
Silicon carbide is a wide bandgap semiconductor ideally suitable for high temperature and
high power applications. An active SiC layer is usually fabricated using halide-assisted …

Silicon chemistry in fluorinated chemical vapor deposition of silicon carbide

P Stenberg, P Sukkaew, I Farkas… - The Journal of …, 2017 - ACS Publications
The use of chlorinated chemical vapor deposition (CVD) chemistry for growth of
homoepitaxial layers of silicon carbide (SiC) has diminished the problem of homogeneous …

Influence of Carbon Source on the Buffer Layer for 4H-SiC Homoepitaxial Growth

S Yang, N Guo, S Zhao, Y Li, M Wei, Y Zhang, X Liu - Materials, 2024 - mdpi.com
In this study, we systematically explore the impact of C/Si ratio, pre-carbonization time, H2
etching time, and growth pressure on the buffer layer and subsequent epitaxial layer of 6 …

Matching precursor kinetics to afford a more robust CVD chemistry: a case study of the C chemistry for silicon carbide using SiF 4 as Si precursor

P Stenberg, Ö Danielsson, E Erdtman… - Journal of Materials …, 2017 - pubs.rsc.org
Chemical vapor deposition (CVD) is one of the technology platforms forming the backbone
of the semiconductor industry and is vital in the production of electronic devices. To upscale …

Perspective—Current Understanding of the Halogenated Deposition Chemistry for Chemical Vapor Deposition of SiC

H Pedersen, L Ojamäe… - ECS Journal of Solid State …, 2020 - iopscience.iop.org
The deposition rate of silicon carbide (SiC) in chemical vapor deposition (CVD) can be
boosted by addition of chlorine. This has been explored and applied for hard coatings and …

Thermochemical properties of halides and halohydrides of silicon and carbon

P Sukkaew, L Ojamäe, O Kordina… - ECS Journal of Solid …, 2015 - iopscience.iop.org
Atomization energies, enthalpies of formation, entropies as well as heat capacities of the SiH
n X m and CH n X m systems, with X being F, Cl and Br, have been studied using quantum …

Defects in silicon carbide grown by fluorinated chemical vapor deposition chemistry

P Stenberg, ID Booker, R Karhu, H Pedersen… - Physica B: Condensed …, 2018 - Elsevier
Point defects in n-and p-type 4H-SiC grown by fluorinated chemical vapor deposition (CVD)
have been characterized optically by photoluminescence (PL) and electrically by deep-level …

Incorporation of dopants in epitaxial SiC layers grown with fluorinated CVD chemistry

P Stenberg, E Janzén, H Pedersen - Journal of Vacuum Science & …, 2017 - pubs.aip.org
Fluorinated chemistry in chemical vapor deposition (CVD) of silicon carbide (SiC) with SiF 4
as Si precursor has been shown to fully eliminate the formation of silicon clusters in the gas …