Novel half‐sandwich η5‐Cp *–rhodium(III) and η5‐Cp *–ruthenium(II) complexes bearing bis(phosphino)amine ligands and their use in the transfer hydrogenation …
Two new half‐sandwich η5‐Cp*–rhodium (III) and η5‐Cp*–ruthenium (II) complexes have
been prepared from corresponding bis (phosphino) amine ligands, thiophene‐2‐(N, N‐bis …
been prepared from corresponding bis (phosphino) amine ligands, thiophene‐2‐(N, N‐bis …
16-Electron pentadienyl-and cyclopentadienyl-ruthenium half-sandwich complexes with bis (imidazol-2-imine) ligands and their use in catalytic transfer hydrogenation
T Glöge, K Jess, T Bannenberg, PG Jones… - Dalton …, 2015 - pubs.rsc.org
Bis (η5-2, 4-dimethylpentadienyl) ruthenium (II),[(η5-C7H11) 2Ru](1,“open ruthenocene”),
which has become accessible in high yield and large quantities via an isoprene-derived …
which has become accessible in high yield and large quantities via an isoprene-derived …
C–H activation of pyrazolyl ligands by Ru (II)
Previously, hydridotris (pyrazolyl) borate (Tp) Ru (II) alkyl and aryl complexes of the type
TpRu (L)(NCMe) R (R= methyl or aryl; L= charge-neutral two-electron donating ligand) were …
TpRu (L)(NCMe) R (R= methyl or aryl; L= charge-neutral two-electron donating ligand) were …
Molecular and electronic structures of donor-functionalized dysprosium pentadienyl complexes
BM Day, NF Chilton, RA Layfield - Dalton Transactions, 2015 - pubs.rsc.org
Two dysprosium complexes,[(C5H4Me) 2Dy (L1)](3) and [(L1) Dy (μ-Cl) 3 {Li (tmeda)}] 2 (4),
with amino-functionalized pentadienyl ligands L1 are described. Crystallographic studies of …
with amino-functionalized pentadienyl ligands L1 are described. Crystallographic studies of …
Contributions to the Chemistry of the Cyclopentadienyl Complex [Cp∧RuCl2]2 (“Cp‐roof” = η5‐1‐Methoxy‐2,4‐tert‐butyl‐3‐neopentylcyclopentadienyl)
The dimeric ruthenium complex [Cp∧ RuCl2] 2 is easily accessible in a one‐pot reaction
from RuCl3 (solv) n and tert‐butylacetylene. It features sterically very demanding “Cp‐roof” …
from RuCl3 (solv) n and tert‐butylacetylene. It features sterically very demanding “Cp‐roof” …
Synthesis and Coordination Chemistry of Pentadienyl Ligands Derived from (1R)-(−)-Myrtenal
AC Fecker, BF Craciun, M Freytag, PG Jones… - …, 2014 - ACS Publications
With the natural product (1 R)-(−)-myrtenal as the starting material, a series of chiral
pentadienes (Pdl*) such as dimethylnopadiene (2a), methylphenylnopadiene (2b), and …
pentadienes (Pdl*) such as dimethylnopadiene (2a), methylphenylnopadiene (2b), and …
Structural influences in lithium pentadienylsilane complexes
BM Day, J Clayden, RA Layfield - Organometallics, 2013 - ACS Publications
Structurally characterized lithium pentadienyls are very rare. We report the molecular
structures of two lithium pentadienyls,[(pmdeta) Li {1-(R3Si) C5H6}](3) and [(pmdeta) Li {1, 5 …
structures of two lithium pentadienyls,[(pmdeta) Li {1-(R3Si) C5H6}](3) and [(pmdeta) Li {1, 5 …
Addition reactions of Cp* Ru (1-5-η-CH2CHCRCHSO2)(R= H, Me) with carbon monoxide, phosphorus, sulfur and nitrogen ligands: Spectroscopic and structural …
BA Paz-Michel, JI de la Cruz-Cruz… - Journal of …, 2016 - Elsevier
A series of chiral compounds Cp* Ru (1-2, 5-η-butadienesulfonyl)(L)(Cp*= C 5 Me 5;
butadienesulfonyl= CH 2 CHCRCHSO 2) were prepared by treating Cp* Ru (1-5-η-CH 2 …
butadienesulfonyl= CH 2 CHCRCHSO 2) were prepared by treating Cp* Ru (1-5-η-CH 2 …
Phosphine-Substituted (η5-Pentadienyl) Manganese Carbonyl Complexes: Geometric Structures, Electronic Structures, and Energetic Properties of the Associative Substitution …
JI de la Cruz Cruz, P Juárez-Saavedra… - …, 2014 - ACS Publications
The molecule (η5-Me2Pdl) Mn (CO) 3 (η5-Me2Pdl= 2, 4-dimethyl-η5-pentadienyl) has been
prepared by a new method and used as a starting material to prepare the molecules (η5 …
prepared by a new method and used as a starting material to prepare the molecules (η5 …
Synthesis, Spectroscopy, Structure, and Reactivity of Azapentadienyl-Rhodium-Phosphine and Azapentadienyl-Iridium-Phosphine Complexes1
JR Bleeke, W Anutrasakda, NP Rath - Organometallics, 2013 - ACS Publications
We report the synthesis, spectroscopy, structure, and reactivity of (1, 2, 3-η3)-(5-tert-
butylazapentadienyl) Rh (PMe3) x (1, x= 2; 4, x= 3) and (1, 2, 3-η3)-(5-tert …
butylazapentadienyl) Rh (PMe3) x (1, x= 2; 4, x= 3) and (1, 2, 3-η3)-(5-tert …