Reversible electron reservoir feature of redox non-innocent ligand is an important event from
the broader perspectives of metal–ligand cooperativity in catalysis as well as in introducing …

Understanding and exploiting the redox properties of uranium is of great importance
because uranium has a wide range of possible oxidation states and holds great potential for …

Two-electron reduction of the amidate-supported U (III) mono (arene) complex U (TDA) 3 (2)
with KC8 yields the anionic bis (arene) complex [K [2.2. 2] cryptand][U (TDA) 2](3)(TDA= N …

Herein, we report the redox reactivity of a multimetallic uranium complex supported by
triphenylsiloxide (− OSiPh3) ligands, where we show that low valent synthons can be …

The high stability of the+ IVoxidation state limits thorium redox reactivity. Here we report the
synthesis and the redox reactivity of two Th (IV) complexes supported by the arene‐tethered …

Reduction of [{η5-1, 2, 4-(Me3Si) 3C5H2} 2UCl2](1) using potassium graphite (KC8) in the
presence of 2, 2′-bipyridine forms the uranium bipyridyl metallocene [{η5-1, 2, 4-(Me3Si) …

The uranium bipyridyl metallocene,[η5-1, 3-(Me3Si) 2C5H3] 2U (bipy)(2), is readily
accessible in good yield by adding potassium graphite (KC8) to a mixture of [η5-1, 3-(Me3Si) …

The concept of oxidation state plays a fundamentally important role in defining the chemistry
of the elements. In the f block of the periodic table, well-known oxidation states in …

U (IV) cyclometalated complexes have shown rich reactivity, but their low oxidation state
analogues still remain rare. Herein, we report the isolation of [K (2.2. 2-cryptand)][UIII {N …

The uranium bipyridyl metallocene,[η5-1, 2, 4-(Me3C) 3C5H2] 2U (bipy)(2), prepared from
[η5-1, 2, 4-(Me3C) 3C5H2] 2UCl2 (1) and 2, 2′-bipyridine in the presence of potassium …