Metal–organic framework glass composites

R Lin, M Chai, Y Zhou, V Chen, TD Bennett… - Chemical Society …, 2023 - pubs.rsc.org
The melting phenomenon in metal–organic frameworks (MOFs) has been recognised as
one of the fourth generation MOF paradigm behaviours. Molten MOFs have high …

Functions and applications of emerging metal–organic-framework liquids and glasses

M Wang, H Zhao, B Du, X Lu, S Ding… - Chemical …, 2023 - pubs.rsc.org
Traditional metal–organic-frameworks (MOFs) have been extensively studied and applied in
various fields across chemistry, biology and engineering in the past decades. Recently, a …

Fabrication of Super‐Sized Metal Inorganic‐Organic Hybrid Glass with Supramolecular Network via Crystallization‐Suppressing Approach

MA Ali, WMW Winters, MA Mohamed… - Angewandte Chemie …, 2023 - Wiley Online Library
Metal coordination compound (MCC) glasses [eg, metal‐organic framework (MOF) glass,
coordination polymer glass, and metal inorganic‐organic complex (MIOC) glass] are …

Modulating liquid–liquid transitions and glass formation in zeolitic imidazolate frameworks by decoration with electron-withdrawing cyano groups

J Song, L Frentzel-Beyme, R Pallach… - Journal of the …, 2023 - ACS Publications
The liquid phase of metal–organic frameworks (MOFs) is key for the preparation of melt-
quenched bulk glasses as well as the shaping of these materials for various applications; …

Hierarchical metal‐organic network‐forming glasses toward applications

YS Wei, CW Ashling, T Watcharatpong… - Advanced Functional …, 2024 - Wiley Online Library
Glassy states of network‐forming coordination polymers (CPs) and metal‐organic
frameworks (MOFs) represent a novel category of amorphous materials. Recent years have …

Glass and liquid chemistry of coordination polymers and MOFs

S Horike - Bulletin of the Chemical Society of Japan, 2023 - academic.oup.com
The chemistry of coordination polymers and metal-organic frameworks (MOFs) has
progressed largely with the development of crystallography. The study of “disordered …

Multi‐stage Transformations of a Cluster‐Based Metal‐Organic Framework: Perturbing Crystals to Glass‐Forming Liquids that Re‐Crystallize at High Temperature

MZ Chen, J Li, S Liao, YH Guo, T Liu, RF Ma… - Angewandte …, 2023 - Wiley Online Library
Glassy and liquid state metal–organic frameworks (MOFs) are emerging type of materials
subjected to intense research for their rich physical and chemical properties. In this report …

A review on the vitrification of metal coordination compounds and their photonic applications

MA Ali, X Liu, J Qiu - Journal of Non-Crystalline Solids, 2022 - Elsevier
The vitrification of metal coordination compounds (MCC) leads to the emerging of a new
family of glass with unique structures and properties. In this review, we discuss the recent …

Melt-Quenched Glass Films of Coordination Polymers as Impermeable Barrier Layers and Protective Anticorrosion Coatings

T Ji, Y Song, J Yan, Y Sun, C Wang, S Chen… - Chemistry of …, 2022 - ACS Publications
The crystal–liquid–glass phase-transition behavior of coordination polymers (CPs) endows
them with unique processing and mechanical properties to prepare functional CP glass …

In situ recrystallization of zero-dimensional hybrid metal halide glass-ceramics toward improved scintillation performance

B Li, J Jin, M Yin, K Han, Y Zhang, X Zhang… - Chemical …, 2023 - pubs.rsc.org
Zero-dimensional (0D) hybrid metal halide (HMH) glasses are emerging luminescent
materials and have gained attention due to their transparent character and ease of …