Highly selective and direct electroreductive ring‐opening carboxylation of epoxides with
CO2 in an undivided cell is reported. This reaction shows broad substrate scopes within …

Carbon dioxide is a nontoxic and abundant chemical and has been widely used as a C1
building block for the synthesis of highly important chemicals. This greenhouse gas also has …

Reported here is the CO2-facilitated radical sequential (3+ 2) annulation of 1, 6-enynes that
proceeds under the concerted catalysis of sulfinate and a photocatalyst (PC) to construct …

Electrocarboxylation reaction, which employs organic electrosynthesis to achieve the
utilization of CO2 as a carboxylative reagent, provides a powerful and efficient tool for the …

The carbon dioxide (CO2) capture and utilization has attracted a great attention in organic
synthesis. Herein, an unpresented transient stabilization effect (TSE) of CO2 is disclosed …

We report nickel-catalyzed cyanation and hydrocyanation methods to prepare aryl nitriles
and vinyl nitriles from aryl halides and alkynes, respectively. Using inexpensive and …

Marine sponge diterpenoid isonitriles are exceptional nitrogenous natural products that
exhibit antiplasmodial activity. Their biosynthesis presents a biosynthetic puzzle: how do the …

Transamidation reactions are often mediated by reactive substrates in the presence of
overstoichiometric activating reagents and/or transition metal catalysts. Here we report the …

Palladium-catalyzed organometallic transformations of free amines are often unsuccessful
due to side reactions, such as oxidation, that can occur. However, the ability to furnish the …

A unique self-detachable protecting group function of CO2 in the selective electrochemical
reduction of azides is reported. By utilizing CO2 as the self-detachable protecting group, the …