New insights into perfluorinated sulfonic-acid ionomers

A Kusoglu, AZ Weber - Chemical reviews, 2017 - ACS Publications
In this comprehensive review, recent progress and developments on perfluorinated sulfonic-
acid (PFSA) membranes have been summarized on many key topics. Although quite well …

A review of PEM fuel cell durability: materials degradation, local heterogeneities of aging and possible mitigation strategies

L Dubau, L Castanheira, F Maillard… - Wiley …, 2014 - Wiley Online Library
Through a tight collaboration between chemical engineers, polymer scientists, and
electrochemists, we address the degradation mechanisms of membrane electrode …

Structure-transport relationship of perfluorosulfonic-acid membranes in different cationic forms

S Shi, AZ Weber, A Kusoglu - Electrochimica Acta, 2016 - Elsevier
Perfluorosulfonic-acid (PFSA) ionomers are widely used as solid electrolytes and ion-
exchange membranes in electrochemical devices, wherein their properties are impacted by …

Investigation of ionomer structure through its dependence on ion exchange capacity (IEC)

E Moukheiber, G De Moor, L Flandin, C Bas - Journal of Membrane …, 2012 - Elsevier
The ion exchange capacity (IEC) of conventional ion-exchange perfluorinated membranes
based on the so-called Long-Side-Chain (LSC) polymers and their Short-Side-Chain (SSC) …

Migration of Ce and Mn ions in PEMFC and its impact on PFSA membrane degradation

M Zatoń, B Prélot, N Donzel, J Rozière… - Journal of The …, 2018 - iopscience.iop.org
The incorporation of cerium and manganese ions in perfluorosulfonic acid (PFSA)
membranes strongly decreases the fluoride ion emission rate from fuel cell membrane …

Durability of Pt3Co/C cathodes in a 16 cell PEMFC stack: Macro/microstructural changes and degradation mechanisms

L Dubau, F Maillard, M Chatenet… - Journal of The …, 2010 - iopscience.iop.org
In this work, we operated a 16-cell proton-exchange membrane fuel cell (PEMFC) stack
based on a Pt/C anode and a cathode under/air at constant current, temperature, relative …

Enhanced chemical durability of perfluorosulfonic acid membranes through incorporation of terephthalic acid as radical scavenger

Y Zhu, S Pei, J Tang, H Li, L Wang, WZ Yuan… - Journal of membrane …, 2013 - Elsevier
Chemical durability of perfluorosulfonic acid (PFSA) membranes is of crucial importance for
their applications in proton exchange membrane fuel cells (PEMFCs). Herein, we report an …

Synthesis of partially fluorinated poly (arylene ether sulfone) multiblock copolymers bearing perfluorosulfonic functions

L Assumma, C Iojoiu, R Mercier… - Journal of Polymer …, 2015 - Wiley Online Library
Partially fluorinated poly (arylene ether sulfone) multiblock copolymers bearing
perfluorosulfonic functions (ps‐PES‐FPES), with ionic exchange capacity (IEC) ranging …

Thermal transitions in perfluorosulfonated ionomer thin-films

M Tesfaye, DI Kushner, BD McCloskey… - ACS macro …, 2018 - ACS Publications
Thin perfluorosulfonated ion-conducting polymers (PFSI ionomers) in energy-conversion
devices have limitations in functionality attributed to confinement-driven and surface …

Polymer Electrolytes Based on the Lithium Form of Nafion Sulfonic Cation-Exchange Membranes: Current State of Research and Prospects for Use in Electrochemical …

OV Bushkova, EA Sanginov, SD Chernyuk… - Membranes and …, 2022 - Springer
The review analyzes and summarizes the results of investgations of lithium-conducting
polymer electrolytes obtained via ion exchange from the initial H+ form of perfluorinated …