Electronic structure of corrole derivatives: insights from molecular structures, spectroscopy, electrochemistry, and quantum chemical calculations
A Ghosh - Chemical Reviews, 2017 - ACS Publications
Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …
Strategies for corrole functionalization
This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …
core, as well as the peripheral positions of the macrocycle. Experimental details for the …
The story of 5d metallocorroles: from metal–ligand misfits to new building blocks for cancer phototherapeutics
Conspectus Porphyrin chemistry is Shakespearean: over a century of study has not withered
the field's apparently infinite variety. Heme proteins continually astonish us with novel …
the field's apparently infinite variety. Heme proteins continually astonish us with novel …
Seven clues to ligand noninnocence: the metallocorrole paradigm
Conspectus Noninnocent ligands do not allow an unambiguous definition of the oxidation
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …
state of a coordinated atom. When coordinated, the ligands also cannot be adequately …
The structural chemistry of metallocorroles: combined X-ray crystallography and quantum chemistry studies afford unique insights
Although they share some superficial structural similarities with porphyrins, corroles,
trianionic ligands with contracted cores, give rise to fundamentally different transition metal …
trianionic ligands with contracted cores, give rise to fundamentally different transition metal …
X-ray absorption spectroscopy as a probe of ligand noninnocence in metallocorroles: the case of copper corroles
The question of ligand noninnocence in Cu corroles has long been a topic of discussion.
Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which …
Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which …
Synthesis, Spectral, Redox, and Sensing Studies of β-Dicyanovinyl-Appended Corroles and Their Metal Complexes
A new family of β-dicyanovinyl (DCV)-appended corroles represented as MTPC (MN)(where
M= 3H, Cu, Ag, and Co (PPh3) and MN= malononitrile and TPC= 5, 10, 15-triphenylcorrole) …
M= 3H, Cu, Ag, and Co (PPh3) and MN= malononitrile and TPC= 5, 10, 15-triphenylcorrole) …
Cobalt-and rhodium-corrole-triphenylphosphine complexes revisited: The question of a noninnocent corrole
A reinvestigation of cobalt–corrole–triphenylphosphine complexes has yielded an
unexpectedly subtle picture of their electronic structures. UV–vis absorption spectroscopy …
unexpectedly subtle picture of their electronic structures. UV–vis absorption spectroscopy …
Tuning Proton Reduction Efficiencies of Copper Corrole in Electrocatalysis via Multiple β-Chloro Substitution
K Sudhakar, PK Panda - ACS Applied Energy Materials, 2022 - ACS Publications
Electrocatalytic hydrogen evolution reaction (HER) is worthy research to produce fuel for
human need. Although copper corroles were first reported two decades ago, still there is a …
human need. Although copper corroles were first reported two decades ago, still there is a …
Electronic structure of cobalt–corrole–pyridine complexes: noninnocent five-coordinate Co (II) corrole–radical states
Two sets of complexes of Co–triarylcorrole–bispyridine complexes, Co [T p XPC](py) 2 and
Co [Br8T p XPC](py) 2 have been synthesized, where T p XPC refers to a meso-tris (para-X …
Co [Br8T p XPC](py) 2 have been synthesized, where T p XPC refers to a meso-tris (para-X …