Palladium-catalyzed carbonylative coupling reactions between Ar–X and carbon nucleophiles

XF Wu, H Neumann, M Beller - Chemical Society Reviews, 2011 - pubs.rsc.org
Palladium-catalyzed carbonylative coupling reactions of aromatic halides and related
compounds have undergone a rapid development during recent years. Nowadays, a …

Ortho-Phosphinobenzenesulfonate: A Superb Ligand for Palladium-Catalyzed Coordination–Insertion Copolymerization of Polar Vinyl Monomers

A Nakamura, TMJ Anselment, J Claverie… - Accounts of chemical …, 2013 - ACS Publications
Ligands, Lewis bases that coordinate to the metal center in a complex, can completely
change the catalytic behavior of the metal center. In this Account, we summarize new …

Controlled polymerization of next-generation renewable monomers and beyond

K Yao, C Tang - Macromolecules, 2013 - ACS Publications
Natural molecular biomass plays an important role in the field of renewable polymers, as
they can be directly used or derivatized as monomers for controlled polymerization, in a way …

Controlled Radical Polymerization of Acrylates and Isocyanides Installs Degradable Functionality into Novel Copolymers

L Čamdžić, EE Stache - Journal of the American Chemical …, 2023 - ACS Publications
Installing ketones into a polymer backbone is a known method for introducing
photodegradability into polymers; however, most current methods are limited to ethylene …

Transition-metal-catalyzed functional polyolefin synthesis: effecting control through chelating ancillary ligand design and mechanistic insights

BP Carrow, K Nozaki - Macromolecules, 2014 - ACS Publications
The incorporation of polar functional groups into polyolefins can significantly alter the
adhesion, barrier and surface properties, dyeability, printability, and compatibility of the …

Photodegradable polar-functionalized polyethylenes

C Wang, J Xia, Y Zhang, X Hu… - National Science Review, 2023 - academic.oup.com
The degradation of plastics has attracted much attention from the global community.
Polyethylenes (PEs), as the most abundant synthetic plastics, are most frequently studied …

Mechanism and origins of ligand-controlled linear versus branched selectivity of iridium-catalyzed hydroarylation of alkenes

G Huang, P Liu - ACS Catalysis, 2016 - ACS Publications
The iridium-catalyzed carbonyl-directed hydroarylation of monosubstituted alkenes
developed by Bower and co-workers [Crisenza, GEM; McCreanor, NG; Bower, JFJ Am …

Catalyst Editing via Post-Synthetic Functionalization by Phosphonium Generation and Anion Exchange for Nickel-Catalyzed Ethylene/Acrylate Copolymerization

P Ghana, S Xiong, A Tekpor, BC Bailey… - Journal of the …, 2024 - ACS Publications
Rapid, efficient development of homogeneous catalysts featuring desired performance is
critical to numerous catalytic transformations but remains a key challenge. Typically, this task …

Ethylene polymerization by 2-iminopyridylnickel halide complexes: synthesis, characterization and catalytic influence of the benzhydryl group

WH Sun, S Song, B Li, C Redshaw, X Hao, YS Li… - Dalton …, 2012 - pubs.rsc.org
A series of 2-(2-benzhydrylbenzenamino) pyridine ligands (L1–L13) was synthesized and
used as bidentate N^ N ligands with nickel halides to afford the corresponding nickel …

Polyethylenes with combined in-chain and side-chain functional groups from catalytic terpolymerization of carbon monoxide and acrylate

M Baur, S Mecking - ACS Macro Letters, 2022 - ACS Publications
Linear polyethylenes with a combination of incorporated in-chain keto as well as side-chain
ester groups are formed by Ni (II)-catalyzed terpolymerization of ethylene, carbon monoxide …