Noncoordinating anions—fact or fiction? A survey of likely candidates
I Krossing, I Raabe - Angewandte Chemie International Edition, 2004 - Wiley Online Library
Is there anything resembling a truly noncoordinating anion? Would it not be great to be able
to prepare any crazy, beautiful, or simply useful cationic species that one has in mind, or has …
to prepare any crazy, beautiful, or simply useful cationic species that one has in mind, or has …
Nichtkoordinierende Anionen–Traum oder Wirklichkeit? Eine Übersicht zu möglichen Kandidaten
I Krossing, I Raabe - Angewandte Chemie, 2004 - Wiley Online Library
Gibt es so etwas wie ein wirklich nichtkoordinierendes Anion? Wäre es nicht großartig, jede
verrückte, schöne oder einfach nur nützliche kationische Spezies herstellen zu können, sei …
verrückte, schöne oder einfach nur nützliche kationische Spezies herstellen zu können, sei …
Tris(trifluoromethyl)borane Carbonyl, (CF3)3BCOSynthesis, Physical, Chemical and Spectroscopic Properties, Gas Phase, and Solid State Structure
M Finze, E Bernhardt, A Terheiden… - Journal of the …, 2002 - ACS Publications
Tris (trifluoromethyl) borane carbonyl,(CF3) 3BCO, is obtained in high yield by the solvolysis
of K [B (CF3) 4] in concentrated sulfuric acid. The in situ hydrolysis of a single bonded CF3 …
of K [B (CF3) 4] in concentrated sulfuric acid. The in situ hydrolysis of a single bonded CF3 …
Synthesis and Properties of the Tetrakis(trifluoromethyl)borate Anion, [B(CF3)4]−: Structure Determination of Cs[B(CF3)4] by Single‐Crystal X‐ray Diffraction
E Bernhardt, G Henkel, H Willner… - … A European Journal, 2001 - Wiley Online Library
Salts of the tetrakis (trifluoromethyl) borate anion, M [B (CF3) 4], M= Li, K, Cs, Ag, have been
prepared by two different routes for the first time. The colorless compounds are thermally …
prepared by two different routes for the first time. The colorless compounds are thermally …
Tests of the MP2 Model and Various DFT Models in Predicting the Structures and B−N Bond Dissociation Energies of Amine−Boranes (X3C)mH3-mB−N(CH3)nH3-n (X = H, F; …
TM Gilbert - The Journal of Physical Chemistry A, 2004 - ACS Publications
Computational studies of amine− boranes (X3C) m H3-m B− N (CH3) n H3-n (X= H, F; m=
0− 3; n= 0− 3) show that the B3LYP model performs poorly in predicting the structures and …
0− 3; n= 0− 3) show that the B3LYP model performs poorly in predicting the structures and …
σ-Bonded metal carbonyl cations and their derivatives: Syntheses and structural, spectroscopic, and bonding principles
H Willner, F Aubke - Organometallics, 2003 - ACS Publications
Homoleptic σ-bonded metal carbonyl cations (σ-carbonyls) and their derivatives have grown
in recent years into a large subgroup of mononuclear metal carbonyl complexes. They are at …
in recent years into a large subgroup of mononuclear metal carbonyl complexes. They are at …
Aryl bromide/triflate selectivities reveal mechanistic divergence in palladium-catalysed couplings; the Suzuki–Miyaura anomaly
G Espino, A Kurbangalieva, JM Brown - Chemical communications, 2007 - pubs.rsc.org
Aryl bromide/triflate selectivities reveal mechanistic divergence in palladium-catalysed
couplings; the Suzuki–Miyaura anomaly - Chemical Communications (RSC Publishing) DOI:10.1039/B701517H …
couplings; the Suzuki–Miyaura anomaly - Chemical Communications (RSC Publishing) DOI:10.1039/B701517H …
Na [B (hfip) 4](hfip= OC (H)(CF 3) 2): a weakly coordinating anion salt and its first application to prepare ionic liquids
S Bulut, P Klose, I Krossing - Dalton Transactions, 2011 - pubs.rsc.org
The fast, high yield synthesis and full characterization of Na [B (hfip) 4](hfip: OC (H)(CF3) 2)
from NaBH4 and hexafluoroisopropanol (hfipH) is presented. By anion metathesis, five [B …
from NaBH4 and hexafluoroisopropanol (hfipH) is presented. By anion metathesis, five [B …
π Acceptor Abilities of Anionic Ligands: Comparisons Involving Anionic Ligands Incorporated into Linear d10 [(NH3)Pd(A)]−, Square Planar d8 [(NN2)Ru(A)]−, and Octahedral d6 …
TM Gilbert - Inorganic Chemistry, 2023 - ACS Publications
Extended transition state-natural orbitals for chemical valence (ETS-NOCV)] data were used
to rank electron acceptor capacities for several potentially synergistic anionic ligands …
to rank electron acceptor capacities for several potentially synergistic anionic ligands …
The Explosive “Inert” Anion CB11(CF3)12-
BT King, J Michl - Journal of the American Chemical Society, 2000 - ACS Publications
We have prepared the icosahedral anion CB11 (CF3) 12-(1-), dodecakistrifluoromethylcarba-
closo-dodecaborate, whose large size, absence of strongly basic sites, sterically protected …
closo-dodecaborate, whose large size, absence of strongly basic sites, sterically protected …