Enantiopure Chiral Au13 Nanoclusters Stabilized by Ditopic N-Heterocyclic Carbenes: Synthesis, Characterization, and Electrocatalytic Reduction of CO2

EL Albright, S Malola, SI Jacob, H Yi… - Chemistry of …, 2024 - ACS Publications
A series of chiral Au13 nanoclusters were synthesized via the direct reduction of chiral
dinuclear Au (I) halide complexes ligated by chiral dioxalone-linked bis-N-heterocyclic …

A Recent Progress in Atomically Precise Silver Nanocluster Assembled Materials

S Mandal, N Alam, AK Das, C Priyanka, P Baidya - Nanoscale, 2024 - pubs.rsc.org
In the dynamic landscape of nanotechnology, atomically precise silver nanoclusters (Ag
NCs) have emerged as a novel and promising category of materials with their fascinating …

Viewing inorganic metal nanoclusters through the lens of molecular chemistry

Y Zhong, Z Wu, X Bai, Y Zhang, J Xie - Materials Today, 2024 - Elsevier
Few-to hundred-atom-composed metal nanoclusters (NCs) lie in the transition regime
between molecular-and nanometer-scales and have attracted intensive attention for their …

Two-Photon and Three-Photon Circular Dichroism of Au38 Gold Nanoclusters Enantiomers

P Obstarczyk, R Kazan, T Bürgi… - Journal of the …, 2024 - ACS Publications
While circular dichroism (CD) and optical activity (OA) are well established as optical effects
used in characterization of chiral media, harmonic generation and multiphoton circular …

Intrinsically chiral thermoresponsive assemblies from achiral clusters: enhanced luminescence and optical activity through tailor-made chiral additives

C Dutta, RV Nataraajan, J Kumar - Chemical Science, 2025 - pubs.rsc.org
Chiral metal clusters, due to their intriguing optical properties and unique resemblance in
size to biomolecules, have attracted a lot of attention in recent times as potential candidates …

Gaussian Process Approach to Constructing Transferable Force Fields for Thiolate-Protected Gold Nanoclusters

Y Wang, DSND Samarasinghe, H Deng… - Journal of Chemical …, 2025 - ACS Publications
Gold nanoparticles can exhibit unique physical and chemical properties, such as plasmon
resonances or photoluminescence. These nanoparticles have many atoms, which leads to …

Construction of dual-chiral covalent organic frameworks for enantioselective separation

J Ma, W Huang, X Huang, N Yang, J Gong, Z Xie… - … of Chromatography A, 2024 - Elsevier
Developing novel chiral stationary phases (CSPs) with versatility is of great importance in
enantiomer separation. This study fabricated a dual-chiral covalent organic framework (PA …

[HTML][HTML] Enantioseparation of organometallic compounds and metal complexes by liquid chromatographic techniques. A review

B Sechi, S Cossu, P Peluso - Journal of Chromatography Open, 2024 - Elsevier
Chiral organometallic compounds and metal complexes, and more recently metal clusters,
have attracted great interest for applications in chemical, biological, medical, and material …

The role of the coupling matrix elements in time-dependent density functional theory on the simulation of core-level spectra of transition metal complexes

S Pak, DR Nascimento - Electronic Structure, 2024 - iopscience.iop.org
Time-dependent density functional theory (TD-DFT) stands out as an efficient tool for
computing core-level spectra in large molecules, particularly transition metal complexes …

Atomically Precise Rhodium‐Gold Carbonyl Nanoclusters: In‐Depth Synthesis and Multivalence Investigation of [Rh16Au6(CO)36]6−, and its Correlation with [Rh10Au(CO)26 …

S Ruggieri, G Bussoli, M Bortoluzzi… - European Journal of …, 2024 - Wiley Online Library
The synthesis of the previously‐reported atomically‐precise [Rh16Au6 (CO) 36] 6−(1)
nanocluster has been optimized by screening different reaction variables like solvent …