Selected developments and medical applications of organic–inorganic hybrid biomaterials based on functionalized spherosilicates

Ł John - Materials Science and Engineering: C, 2018 - Elsevier
Well-defined and tailor-made spherosilicates and POSS-based (POSS= Polyhedral
Oligomeric Silsesquioxanes)(nano) composites with interesting chemical and mechanical …

Ionic silsesquioxanes: Preparation, structure control, characterization, and applications

Y Kaneko - Polymer, 2018 - Elsevier
This feature article explains the preparation, structural control, characterization, and
applications of ionic silsesquioxane (SQ) polymers and oligomers. Soluble rod-and ladder …

Porous silsesquioxane–imine frameworks as highly efficient adsorbents for cooperative iodine capture

M Janeta, W Bury, S Szafert - ACS applied materials & interfaces, 2018 - ACS Publications
The efficient capture and storage of radioactive iodine (129I or 131I), which can be formed
during nuclear energy generation or nuclear waste storage, is of paramount importance …

A novel polyhedral oligomeric silsesquioxane antioxidant based on amide-linked hindered phenols and its anti-oxidative behavior in polyamide 6, 6

J Zhang, H Fan, J Bai, X Liu, Y Ding, M Yang - Polymer Degradation and …, 2024 - Elsevier
A novel polyhedral oligomeric sesquisiloxane (POSS) antioxidant based on amide-linked
hindered phenols (HPAm-POSS) was successfully synthesized via a nucleophilic …

Hydroxyalkyl-substituted double-decker silsesquioxanes: effective separation of cis and trans isomers

A Władyczyn, A Gągor, K Ślepokura… - Inorganic Chemistry …, 2022 - pubs.rsc.org
In this work, we report the preparation, isolation, and characterization of a family of double-
decker silsesquioxane architectures starting from the previously reported DDSQ-Me2H2 …

Adhesive properties of poly (methyl silsesquioxanes)/bio-based epoxy nanocomposites

T Aziz, H Fan, F Haq, FU Khan, A Numan, M Iqbal… - Iranian Polymer …, 2020 - Springer
Abstract Poly (methyl silsesquioxanes), PMSQ, are cyclic siloxanes with unusual features
that are also widely known as silsesquioxanes due to their organic peripheral and inorganic …

Multifunctional imine-POSS as uncommon 3D nanobuilding blocks for supramolecular hybrid materials: synthesis, structural characterization, and properties

M Janeta, Ł John, J Ejfler, T Lis, S Szafert - Dalton Transactions, 2016 - pubs.rsc.org
In this article, we report on the chemistry and the spectroscopic properties of well-defined
imino-functionalized polyoctahedral oligomeric silsesquioxanes (imine-POSS) with various …

Corner‐and Side‐Opened Cage Silsesquioxanes: Structural Effects on the Materials Properties

H Imoto, Y Ueda, Y Sato, M Nakamura… - European Journal of …, 2020 - Wiley Online Library
Open‐cage silsesquioxane, in which traditional closed‐cage silsesquioxane is partially
hydrolyzed, is a promising class of building blocks for constructing organic‐inorganic …

Preparation of ammonium-functionalized polyhedral oligomeric silsesquioxanes with high proportions of cagelike decamer and their facile separation

K Imai, Y Kaneko - Inorganic Chemistry, 2017 - ACS Publications
In this study, we found that ammonium-functionalized polyhedral oligomeric silsesquioxanes
(POSSs; 2Am-POSS and Am-POSS) with high proportions of cagelike decamer (T10-POSS; …

Synthesis and microstructural properties of the scaffold based on a 3-(trimethoxysilyl) propyl methacrylate–POSS hybrid towards potential tissue engineering …

M Janeta, M Rajczakowska, J Ejfler, D Łydżba… - RSC …, 2016 - pubs.rsc.org
The aim of this work was to develop an efficient approach to prepare a macroporous scaffold
for sophisticated bone replacement, avoiding a long-lasting and complex methodology …