Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

Transition metal catalysis is of utmost importance for the development of sustainable
processes in academia and industry. The activity and selectivity of metal complexes are …

The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

Abstract Transition-metal-catalysed, non-enzymatic transformations of C–H and C= C bonds
to C–N bonds through nitrene transfer (NT) are powerful synthetic tools to prepare valuable …

Radical cascade reactions are an attractive tool for the rapid construction of complex
molecular architectures. Although a large number of powerful radical cascades have been …

Chiral allenes are important structural motifs frequently found in natural products,
pharmaceuticals, and other organic compounds. Asymmetric 1, 4-difunctionalization of 1, 3 …

Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …

The copper-catalyzed enantioselective intermolecular radical 1, 2-carboamination of
alkenes with readily accessible alkyl halides is an appealing strategy for producing chiral …

Control of enantioselectivity remains a major challenge in radical chemistry. The emergence
of metalloradical catalysis (MRC) offers a conceptually new strategy for addressing this and …

C 4-Symmetrical dirhodium (II) tetracarboxylates are highly efficient catalysts for the
asymmetric intermolecular aziridination of substituted alkenes with sulfamates. The reaction …