Electrografting: a powerful method for surface modification

D Belanger, J Pinson - Chemical Society Reviews, 2011 - pubs.rsc.org
Electrografting refers to the electrochemical reaction that permits organic layers to be
attached to solid conducting substrates. This definition can be extended to reactions …

Silicon surface modification and characterization for emergent photovoltaic applications based on energy transfer

W Peng, SM Rupich, N Shafiq, YN Gartstein… - Chemical …, 2015 - ACS Publications
2.1 Background There is already a wealth of information on the wet chemical cleaning of Si
for semiconductor processing,(14, 15) but there is less on subsequent modification methods …

What a difference a bond makes: the structural, chemical, and physical properties of methyl-terminated Si (111) surfaces

KT Wong, NS Lewis - Accounts of chemical research, 2014 - ACS Publications
Conspectus The chemical, electronic, and structural properties of surfaces are affected by
the chemical termination of the surface. Two-step halogenation/alkylation of silicon provides …

Reactivity of selectively terminated single crystal silicon surfaces

KA Perrine, AV Teplyakov - Chemical Society Reviews, 2010 - pubs.rsc.org
As the cornerstone of multiple practical applications, silicon single crystal surfaces have
attracted the interest of scientific and engineering communities for several decades. The …

Functionalization of Oxide‐Free Silicon Surfaces for Biosensing Applications

A Henriksson, P Neubauer… - Advanced Materials …, 2021 - Wiley Online Library
As an alternative to standard silicon biofunctionalization protocol based on alkoxysilanes
that bind to SiO2 on oxidized silicon substrates, several protocols to form bifunctional …

Synthesis, characterization, and reactivity of ethynyl-and propynyl-terminated Si (111) surfaces

NT Plymale, YG Kim, MP Soriaga… - The Journal of …, 2015 - ACS Publications
Ethynyl-and propynyl-terminated Si (111) surfaces synthesized using a two-step
halogenation/alkylation method have been characterized by transmission infrared …

Thermal stability of organic monolayers grafted to Si (111): insights from ReaxFF reactive molecular dynamics simulations

FA Soria, W Zhang, ACT Van Duin… - ACS applied materials & …, 2017 - ACS Publications
We used the ReaxFF reactive molecular dynamics simulations to investigate the chemical
mechanisms and kinetics of thermal decomposition processes of silicon surfaces grafted …

Distinguishing Organomagnesium Species in the Grignard Addition to Ketones with X‐Ray Spectroscopy

L Restaino, R Mincigrucci… - Chemistry–A European …, 2024 - Wiley Online Library
The addition of Grignard reagents to ketones is a well‐established textbook reaction.
However, a comprehensive understanding of its mechanism has only recently begun to …

Study of organic grafting of the silicon surface from 4-nitrobenzene diazonium tetrafluoroborate

FA El Hadj, A Amiar, M Cherkaoui, JN Chazalviel… - Electrochimica …, 2012 - Elsevier
The hydrogenated silicon surface has outstanding electronic properties. However, its
resistance to oxidation is insufficient. An alternative is the substitution of the SiH bonds with …

Anodic methods for covalent attachment of ethynylferrocenes to electrode surfaces: comparison of ethynyl activation processes

MV Sheridan, K Lam, M Sharafi, ST Schneebeli… - Langmuir, 2016 - ACS Publications
The electrochemical oxidation of ferrocenes having an H-or Li-terminated ethynyl group has
been studied, especially as it relates to their covalent anchoring to carbon surfaces. The …